{"id":"W2027810508","doi":"10.1021/ic030020c","title":"Copper-63 NMR Line width Study of the Copper(I)−Acetonitrile System","year":2003,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Trifluoromethanesulfonate; Acetonitrile; Perchlorate; Copper; Ion; Inorganic chemistry; Line width; Chloride; Solvent; Proton NMR; Analytical Chemistry (journal); Physical chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001671377,0.0002706326,0.0003591032,0.0000136928,0.00008806164,0.00001732519,0.0007151568,0.0001856885,0.0002389554],"category_scores_gemma":[0.0003170673,0.0001993271,0.0001064153,0.0002468121,0.0000726555,0.00004173986,0.0001954609,0.0004349651,0.00002765675],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002799943,"about_ca_system_score_gemma":0.00009242672,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005346402,"about_ca_topic_score_gemma":0.000006365271,"domain_scores_codex":[0.9984772,0.00004315318,0.0004473081,0.0003331674,0.0003685681,0.0003305663],"domain_scores_gemma":[0.9986091,0.000071283,0.0001559793,0.0009813393,0.0000884761,0.00009382007],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002011577,0.0002382621,0.0005425061,0.000297263,0.00009724014,0.000005511836,0.0003975286,0.0006033073,0.9971526,0.00004134843,0.000524619,0.00007967598],"study_design_scores_gemma":[0.001189485,0.0000336745,0.00009675071,0.0001403108,0.00006704773,0.00006236807,0.001952379,0.001706126,0.993682,0.000009954899,0.0007934273,0.0002664959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9884397,0.0005907427,0.00002766239,0.00003710199,0.0002264091,0.0002596482,0.00001955118,0.0002045596,0.01019457],"genre_scores_gemma":[0.997269,0.0000036622,0.00004137246,0.00002441628,0.0001037238,0.00001966475,0.000004209758,0.00006596769,0.002468023],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008829207,"threshold_uncertainty_score":0.8128324,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007433540777020629,"score_gpt":0.1963028932299877,"score_spread":0.188869352452967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}