{"id":"W2028089943","doi":"10.1021/om9009747","title":"Fast Kinetics Study of the Reactions of Transient Silylenes with Alcohols. Direct Detection of Silylene−Alcohol Complexes in Solution","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Silylene; Kinetic isotope effect; Alcohol; Reaction rate constant; Methanol; Isotopomers; Kinetics; Catalysis; Molecule; Medicinal chemistry; Deuterium; Photochemistry; Organic chemistry; Silicon","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001921082,0.000240605,0.0005175321,0.0001963771,0.00007676623,0.00001638432,0.0004057485,0.0001340191,0.0005953183],"category_scores_gemma":[0.0001102087,0.0001852253,0.0001242455,0.0009690622,0.0002196203,0.000116386,0.00007966141,0.0002555508,0.000001206088],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004525179,"about_ca_system_score_gemma":0.00005978505,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002389338,"about_ca_topic_score_gemma":0.001506493,"domain_scores_codex":[0.9981333,0.00005111358,0.0008425261,0.0003102389,0.0004608502,0.0002019791],"domain_scores_gemma":[0.9981591,0.0001419236,0.0006730899,0.0007134078,0.0002609318,0.00005157556],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000551694,0.002108635,0.02253081,0.0001260881,0.0001201935,4.470727e-7,0.0009411255,0.00007961196,0.9725896,0.00004560145,6.499413e-7,0.00140211],"study_design_scores_gemma":[0.000763859,0.0001510733,0.1951281,0.00005241681,0.0001297448,0.000007870407,0.0009222978,0.0001107762,0.802158,0.000008061234,0.0004080903,0.0001596875],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979337,0.0000250606,0.0001626693,0.00005563079,0.0001415068,0.0002429612,0.00005458125,0.00002834811,0.001355581],"genre_scores_gemma":[0.9995024,0.00002710983,0.0001361157,0.00000499416,0.00004566092,0.00001885199,0.00001346375,0.00004494095,0.000206476],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1725973,"threshold_uncertainty_score":0.7553267,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01665659323736346,"score_gpt":0.2254958556506136,"score_spread":0.2088392624132501,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}