{"id":"W2028089943","doi":"10.1021/om9009747","title":"Fast Kinetics Study of the Reactions of Transient Silylenes with Alcohols. Direct Detection of Silylene−Alcohol Complexes in Solution","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Silylene; Kinetic isotope effect; Alcohol; Reaction rate constant; Methanol; Isotopomers; Kinetics; Catalysis; Molecule; Medicinal chemistry; Deuterium; Photochemistry; Organic chemistry; Silicon","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003665772,0.0005434287,0.0004173601,0.0001780802,0.00009157832,0.0003752304,0.0003322167,0.0002966365,0.001279883],"category_scores_gemma":[0.0007192577,0.0002694997,0.0002704232,0.000158653,0.0002875649,0.0006075108,0.0002284165,0.0006494701,0.0004700497],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004119622,"about_ca_system_score_gemma":0.000236959,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000607228,"about_ca_topic_score_gemma":0.0003727685,"domain_scores_codex":[0.9998021,0.00002838007,0.000008357637,0.00005426422,0.0000659884,0.0000409568],"domain_scores_gemma":[0.9996839,0.0001467408,0.0000547992,0.00002124787,0.00006002562,0.00003323692],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001060994,0.00002065004,0.0002268546,0.00006510783,0.00001101271,0.00003645071,0.00005914481,0.0002044631,0.9970572,0.0001479116,0.0000273478,0.002037782],"study_design_scores_gemma":[0.00001020847,0.0002004769,0.0007151578,0.000003436029,0.00000844738,0.00004833252,0.00002233783,0.00318481,0.9950948,0.00003924324,0.000665763,0.000007100902],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9745128,0.001739837,0.0207525,0.00008463095,0.00002981145,0.0001043668,0.000277857,0.0002954153,0.002202807],"genre_scores_gemma":[0.9907095,0.0009758355,0.005579134,0.00002780762,0.000008469578,0.00005343528,0.0002247057,0.0000307096,0.002390273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001279883,"threshold_uncertainty_score":0.00428164,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01665659323736346,"score_gpt":0.2254958556506136,"score_spread":0.2088392624132501,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}