{"id":"W2028287044","doi":"10.1139/v05-094","title":"Microwave-accelerated, palladium-catalyzed carbonylative cyclization reactions of 2-iodophenol with alkynes Rapid and efficient synthesis of chromen-2-one derivatives","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Multicomponent Synthesis of Heterocycles","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Palladium; Carbonylation; Catalysis; Carbon monoxide; Molybdenum; Monoxide; Microwave; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002081832,0.0005621077,0.0002233755,0.0004001542,0.0001825884,0.0001820535,0.0002645386,0.000173216,0.001766344],"category_scores_gemma":[0.0001303029,0.0001686883,0.0002188121,0.0002550845,0.0002111158,0.0002120341,0.0002828287,0.0003489996,0.0004869607],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002375121,"about_ca_system_score_gemma":0.0002896981,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005176527,"about_ca_topic_score_gemma":0.001581347,"domain_scores_codex":[0.9998856,0.0000159497,0.000006815177,0.00002039034,0.0000325204,0.00003873999],"domain_scores_gemma":[0.9999324,0.00001052211,0.00001172718,0.00001329913,0.000009623735,0.00002248109],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004862682,0.0000275005,0.00009354767,0.00006252035,0.000010544,0.0001598835,0.00003834531,0.0003738292,0.994395,0.0003885935,0.00008566458,0.004316026],"study_design_scores_gemma":[0.00001885443,0.0001739149,0.0007838491,0.000003314092,0.00001046773,0.0001700068,0.000009627396,0.0004725779,0.9960271,0.00004963868,0.002273927,0.000006645035],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9690089,0.002364525,0.02099967,0.00008581134,0.00004354364,0.0001388843,0.0002436101,0.0002673251,0.006847734],"genre_scores_gemma":[0.9829211,0.001530931,0.01061162,0.00002502546,0.00001217129,0.00005284186,0.0001795603,0.00003594119,0.004630855],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001766344,"threshold_uncertainty_score":0.005909026,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01602752266568188,"score_gpt":0.2120555167525791,"score_spread":0.1960279940868972,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}