{"id":"W2028367566","doi":"10.1002/pola.22382","title":"An efficient synthesis of telechelic poly (<i>N</i>‐isopropylacrylamides) and its application to the preparation of α,ω‐dicholesteryl and α,ω‐dipyrenyl polymers","year":2007,"lang":"en","type":"article","venue":"Journal of Polymer Science Part A Polymer Chemistry","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Polymer chemistry; Chain transfer; Aminolysis; Chemistry; Diethylene glycol; Telechelic polymer; Dispersity; End-group; Poly(N-isopropylacrylamide); Polymer; Pyrene; Copolymer; Reversible addition−fragmentation chain-transfer polymerization; Polymerization; Aqueous solution; Radical polymerization; Ethylene glycol; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001419815,0.000432049,0.0001154952,0.0001612034,0.00009397476,0.0001864059,0.0001556124,0.0002789121,0.000647634],"category_scores_gemma":[0.0001968155,0.0001772792,0.0002259683,0.0001236734,0.0001563096,0.0002480089,0.0002207772,0.0004552733,0.0004275473],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000183803,"about_ca_system_score_gemma":0.0001504669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001576376,"about_ca_topic_score_gemma":0.000261935,"domain_scores_codex":[0.9998999,0.00001642551,0.000008358838,0.00002855928,0.00002662622,0.0000202201],"domain_scores_gemma":[0.9998221,0.00002941459,0.00007612238,0.00002119706,0.00002168381,0.00002945883],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006760305,0.000003162508,0.00001200876,0.00001231183,8.71193e-7,0.00001236037,0.000004431377,0.0000284674,0.9992653,0.00003241534,0.000005732627,0.0006162808],"study_design_scores_gemma":[0.00000258811,0.00003401642,0.0002669387,0.000001289969,0.000002838571,0.00008184196,0.000001927069,0.0002199517,0.9988844,0.00001124144,0.0004915333,0.000001343238],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.963291,0.001486099,0.03108356,0.00008452371,0.0000379193,0.00009544117,0.0002083929,0.0001871462,0.003526004],"genre_scores_gemma":[0.9751061,0.001038505,0.02064514,0.00007035632,0.00001887501,0.00006221293,0.000326011,0.00005394684,0.002678848],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000647634,"threshold_uncertainty_score":0.002166569,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006617066356228157,"score_gpt":0.2657351257093937,"score_spread":0.2591180593531655,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}