{"id":"W2028870293","doi":"10.1002/wcms.79","title":"Mechanisms of branch formation in metal‐catalyzed ethene polymerization","year":2011,"lang":"en","type":"article","venue":"Wiley Interdisciplinary Reviews Computational Molecular Science","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Methylaluminoxane; Macromonomer; Polymer chemistry; Catalysis; Oligomer; Polymerization; Copolymer; Monomer; Polyethylene; Chemistry; Polymer; Olefin fiber; Chain transfer; Carbon chain; Polymer science; Materials science; Radical polymerization; Organic chemistry; Metallocene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006264522,0.0001960652,0.0004238494,0.0003497007,0.0001214608,0.0000273194,0.0006570895,0.0000456894,0.002002769],"category_scores_gemma":[0.00008286678,0.0001780977,0.0001980242,0.00121629,0.0003249777,0.0005517886,0.0004805367,0.00009507613,0.00004157953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008048402,"about_ca_system_score_gemma":0.00006646843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001067591,"about_ca_topic_score_gemma":0.000004734139,"domain_scores_codex":[0.9979594,0.00005912139,0.000823492,0.0004243893,0.0004964168,0.0002371998],"domain_scores_gemma":[0.9989401,0.00003480593,0.0004170191,0.0004002211,0.0001232364,0.00008466301],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001581868,0.0001868213,0.0000296549,0.0001563053,0.00001688328,0.000005569952,0.001382196,0.0003345416,0.9440666,0.01446759,0.000001900126,0.0393361],"study_design_scores_gemma":[0.00044066,0.00006265089,0.002111525,0.0007357086,0.00008703084,0.00006226848,0.0003132678,0.02397782,0.8336945,0.1379597,0.00007003688,0.0004847528],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4959204,0.00250102,0.4905132,0.0001206453,0.0000967939,0.0002892771,0.00002230762,0.00004233538,0.01049408],"genre_scores_gemma":[0.990159,0.00005036522,0.009584593,0.00003449126,0.000006567169,0.00004562921,0.0000739307,0.00001416558,0.00003129751],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4942386,"threshold_uncertainty_score":0.9989095,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02928038752783601,"score_gpt":0.2777377805826662,"score_spread":0.2484573930548302,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}