{"id":"W2028945914","doi":"10.1021/ja900857h","title":"Formation of Carbocycles by Intramolecular Conjugate Displacement: Scope and Mechanistic Insights","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Carbanion; Substituent; Leaving group; Intramolecular force; Allylic rearrangement; Michael reaction; Stereochemistry; Acceptor; Nucleophile; Ring (chemistry); Heteroatom; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003891332,0.0006386936,0.0003023461,0.0002583387,0.0001937506,0.0005643613,0.0005878135,0.0004771907,0.001854808],"category_scores_gemma":[0.0004052302,0.0001736941,0.0003303671,0.0001982982,0.0006868411,0.001193785,0.0006739497,0.001065766,0.0003992277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004440232,"about_ca_system_score_gemma":0.0002077103,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002047623,"about_ca_topic_score_gemma":0.0003278274,"domain_scores_codex":[0.9998111,0.00003654118,0.00001327584,0.00005410524,0.00002944952,0.00005554902],"domain_scores_gemma":[0.9998451,0.00006023695,0.00002797338,0.00002954043,0.00001282301,0.0000241932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004016935,0.0006107467,0.001416933,0.001773738,0.0001151597,0.001421073,0.0007954896,0.004139333,0.8488146,0.04491274,0.001158599,0.09443988],"study_design_scores_gemma":[0.00005000992,0.001242495,0.001003202,0.00004899729,0.00005344914,0.001690548,0.0001460731,0.002775772,0.9616656,0.002040108,0.02924008,0.00004381997],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8564975,0.04455268,0.05043457,0.0007226707,0.0002168523,0.0004150645,0.0002694211,0.000282248,0.04660903],"genre_scores_gemma":[0.9731179,0.01229378,0.01110745,0.0001697089,0.00004063435,0.00007571756,0.0001149896,0.00003037468,0.003049579],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001854808,"threshold_uncertainty_score":0.006204963,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004005793599610449,"score_gpt":0.2100303136773259,"score_spread":0.2060245200777155,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}