{"id":"W202925445","doi":"10.1007/0-306-46881-6_48","title":"Minimization of side reactions during removal of the formyl protecting group from the ε-amino group of lysine","year":2006,"lang":"en","type":"book-chapter","venue":"Kluwer Academic Publishers eBooks","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Protecting group; Lysine; Chemistry; Peptide; Side chain; Cleavage (geology); Amino acid; Peptide synthesis; Group (periodic table); Combinatorial chemistry; Stereochemistry; Organic chemistry; Biochemistry; Biology; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003556814,0.0002923245,0.0004681826,0.00007302943,0.0001134796,0.00002394,0.00066779,0.000819244,0.00003315818],"category_scores_gemma":[0.0003300166,0.0001975981,0.0005553133,0.00005997824,0.0003148206,0.00001720369,0.0003081849,0.00069722,3.248735e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004214293,"about_ca_system_score_gemma":0.00005989663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004436368,"about_ca_topic_score_gemma":0.00005773751,"domain_scores_codex":[0.9979597,0.00006378107,0.0009403686,0.0004299444,0.0003949769,0.0002111976],"domain_scores_gemma":[0.9977077,0.0001071914,0.001310721,0.000666493,0.0001631094,0.00004476002],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005908613,0.00001788875,0.000213887,0.00009110626,0.0003684046,6.86753e-7,0.00006013438,0.00002504902,0.9931811,0.0003853924,0.001674706,0.003922526],"study_design_scores_gemma":[0.0008107702,0.00005793538,0.001700886,0.0008755659,0.000938142,0.00002895478,0.0001738312,0.00007530712,0.8290412,0.004049321,0.1616636,0.0005844783],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5475606,0.002186863,0.0006893281,0.0004623207,0.0003180499,0.001206782,0.0003881709,0.00003469995,0.4471532],"genre_scores_gemma":[0.9254473,0.00006417475,0.0003611882,0.00006918215,0.0006440987,0.00002766159,0.0003331634,0.0000823618,0.07297089],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3778867,"threshold_uncertainty_score":0.8057815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.010585653588066,"score_gpt":0.2054829984250775,"score_spread":0.1948973448370115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}