{"id":"W2029385054","doi":"10.1021/ic040032d","title":"Electrochemistry of Metal Phthalocyanines in Organic Solvents at Variable Pressure","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; University of Calgary","funders":"","keywords":"Chemistry; Phthalocyanine; Electrochemistry; Nernst equation; Reaction rate constant; Metal; Solvent; Standard electrode potential; Inorganic chemistry; Analytical Chemistry (journal); Electrode; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008555216,0.0003201445,0.0004797667,0.00002447925,0.00007876338,0.00001637175,0.0005894459,0.0003370209,0.008036568],"category_scores_gemma":[0.0001004385,0.0003328621,0.000163664,0.0006323315,0.00009768704,0.00006734086,0.0002127252,0.0004331759,0.00004018419],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002984422,"about_ca_system_score_gemma":0.0002140448,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005254769,"about_ca_topic_score_gemma":0.00001312977,"domain_scores_codex":[0.9979465,0.000004690027,0.0006142985,0.0005869116,0.0003405904,0.0005069932],"domain_scores_gemma":[0.9987753,0.00004687603,0.0002655971,0.0006809886,0.00008942155,0.0001418271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002378878,0.0004076008,0.001395078,0.0004129916,0.0001577274,0.000005060795,0.00004459405,0.00003960396,0.9973543,0.00007593412,0.00005945409,0.0000238705],"study_design_scores_gemma":[0.000938895,0.000006343123,0.00003967666,0.00008406652,0.0001568341,0.00007261988,0.00004162506,0.00003087469,0.9953629,0.001426286,0.001527012,0.0003128798],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825633,0.0010878,0.00008181448,0.00009281171,0.00000837332,0.00004993297,0.00003678844,0.00008349094,0.01599565],"genre_scores_gemma":[0.9929135,0.00006522673,0.0002763381,0.00002608073,0.0001325638,0.00003602669,0.0002017012,0.00004771917,0.0063008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01035021,"threshold_uncertainty_score":0.9999123,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00438158785646551,"score_gpt":0.2043353576409107,"score_spread":0.1999537697844452,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}