{"id":"W2029610451","doi":"10.1021/ma0519617","title":"End Group Effect on the Thermal Response of Narrow-Disperse Poly(<i>N</i>-isopropylacrylamide) Prepared by Atom Transfer Radical Polymerization","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":446,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Atom-transfer radical-polymerization; Cloud point; Differential scanning calorimetry; Polymer chemistry; Chemistry; Polymerization; Radical polymerization; Poly(N-isopropylacrylamide); Turbidimetry; End-group; Aqueous solution; Enthalpy; Copolymer; Polymer; Physical chemistry; Thermodynamics; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002041635,0.0003115783,0.0002882498,0.0000467476,0.0001647403,0.00004199284,0.0002777252,0.0001655195,0.001012085],"category_scores_gemma":[0.0000523934,0.0002273097,0.0001740246,0.0001575926,0.0002547019,0.00009310511,0.0000274203,0.000154204,0.00001498762],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004070858,"about_ca_system_score_gemma":0.00002506173,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001440249,"about_ca_topic_score_gemma":0.000008542703,"domain_scores_codex":[0.9982001,0.0002882628,0.0004142018,0.0003882836,0.0003787445,0.0003304359],"domain_scores_gemma":[0.9988888,0.0004461137,0.0001234252,0.0004576596,0.00002134133,0.00006264886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001982282,0.0001891443,0.0009267863,0.00004674216,0.00003268617,0.000009670468,0.000235571,0.000006052091,0.9912304,0.001341207,0.0000862317,0.003913183],"study_design_scores_gemma":[0.0006168065,0.0001555788,0.00143309,0.00006323007,0.00004452686,0.000008497775,0.00004626627,0.0001093616,0.9952618,0.00002554138,0.001988618,0.0002466515],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994371,0.0006752391,0.001546034,0.000362643,0.00005473707,0.0001716257,0.0001826131,0.00008260609,0.002553533],"genre_scores_gemma":[0.9986875,0.000007626617,0.00003612981,0.0001476679,0.00009897572,0.00006726486,0.0002637928,0.00006797857,0.0006230688],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004316526,"threshold_uncertainty_score":0.9999011,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003628096203586728,"score_gpt":0.198239747733624,"score_spread":0.1946116515300373,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}