{"id":"W2029714721","doi":"10.1007/bf03245966","title":"Reductive amination of aldehydes with sodium borohydride and lithium aluminum hydride in the presence of lithium perchlorate","year":2007,"lang":"en","type":"article","venue":"Journal of the Iranian Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"","keywords":"Reductive amination; Chemistry; Sodium borohydride; Lithium (medication); ALUMINUM HYDRIDE; Lithium perchlorate; Diethyl ether; Borohydride; Hydride; Amination; Reducing agent; Organic chemistry; Inorganic chemistry; Ion; Catalysis; Electrochemistry; Hydrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003703155,0.000632645,0.0003495997,0.0003278146,0.0003072268,0.0001719535,0.000526406,0.000334298,0.001417018],"category_scores_gemma":[0.0001935953,0.000206618,0.0003512202,0.0002349431,0.000279359,0.0004390671,0.0004650344,0.0004849126,0.0005972155],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003996655,"about_ca_system_score_gemma":0.0004407316,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008377942,"about_ca_topic_score_gemma":0.001804229,"domain_scores_codex":[0.9997879,0.00003948243,0.00002044078,0.00002540748,0.00003293053,0.00009388787],"domain_scores_gemma":[0.9999038,0.00001340353,0.00002631524,0.00001287861,0.00002284566,0.0000206871],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007541399,0.000069685,0.0003353441,0.0003889862,0.00004203612,0.0004385386,0.0002386542,0.0003574328,0.9884715,0.00144877,0.0002744678,0.007180485],"study_design_scores_gemma":[0.00003275054,0.0003354271,0.0004602705,0.000006758032,0.00002067045,0.0002171789,0.00005552248,0.0002709889,0.9950235,0.000131898,0.003432444,0.00001260921],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9763007,0.002565804,0.01094101,0.0004669246,0.0001217696,0.00007492777,0.0002370785,0.0002438435,0.009047992],"genre_scores_gemma":[0.9937062,0.0007723668,0.002637798,0.00005357023,0.00001572873,0.00001769493,0.0002688759,0.0000142405,0.002513549],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001417018,"threshold_uncertainty_score":0.004740357,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008796684346681525,"score_gpt":0.2341063625744311,"score_spread":0.2253096782277496,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}