{"id":"W2029774337","doi":"10.1002/chin.200530099","title":"Enantioselective Friedel—Crafts Alkylation Reactions Catalyzed by a Chiral Nonracemic C<sub>2</sub>‐Symmetric 2,2′‐Bipyridyl Copper(II) Complex.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Enantioselective synthesis; Friedel–Crafts reaction; Catalysis; Copper; Alkylation; Organic chemistry; Stereochemistry; Medicinal chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002061752,0.0005265852,0.000326033,0.0002121809,0.00026995,0.0002580244,0.0004339071,0.0002917893,0.002461308],"category_scores_gemma":[0.00021822,0.0002026994,0.0001637115,0.000243984,0.0002492929,0.0003800236,0.0002895653,0.0005905559,0.0009194748],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006889832,"about_ca_system_score_gemma":0.0003945265,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001452682,"about_ca_topic_score_gemma":0.002842045,"domain_scores_codex":[0.9998484,0.00002104091,0.000007744216,0.00002324046,0.00002692251,0.00007260065],"domain_scores_gemma":[0.999941,0.00001220355,0.00001733317,0.000009807624,0.000007981789,0.00001172074],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005590424,0.00012957,0.0002472276,0.0003592628,0.00005246879,0.0006171652,0.0001962847,0.00125729,0.9636869,0.007023739,0.004204837,0.02166615],"study_design_scores_gemma":[0.00008471132,0.0001587562,0.0005421069,0.0000095949,0.00002064795,0.0002729752,0.00002285325,0.001437711,0.9875757,0.0004030574,0.009452877,0.00001898589],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9071536,0.005167306,0.02385236,0.0007095556,0.0003855054,0.000197289,0.0008348777,0.0008905213,0.06080899],"genre_scores_gemma":[0.9881373,0.001469756,0.003895412,0.00006871231,0.00002734131,0.00002342961,0.0001988075,0.00005134147,0.006127908],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002461308,"threshold_uncertainty_score":0.008233905,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01387318941496408,"score_gpt":0.2354709282397465,"score_spread":0.2215977388247824,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}