{"id":"W2029835761","doi":"10.1021/om000274v","title":"Electronic Structures of Transition Metal Phosphorus Monoxide Complexes","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Monoxide; Transition metal; Carbon monoxide; Phosphorus; Density functional theory; Metal; Computational chemistry; Crystallography; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005152456,0.00009621294,0.0001447652,0.00001177844,0.00003996677,0.00001019354,0.0001245724,0.00004620616,0.0400048],"category_scores_gemma":[0.000005615615,0.00008514247,0.00006471139,0.0001932926,0.00008287359,0.0001178431,0.00001518754,0.00005924483,0.0001493797],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005911846,"about_ca_system_score_gemma":0.000004786082,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007541684,"about_ca_topic_score_gemma":0.00001052631,"domain_scores_codex":[0.9992941,0.00001699097,0.0001743787,0.0001648108,0.000170449,0.0001792947],"domain_scores_gemma":[0.9997602,0.00001482527,0.00004662472,0.0001315198,0.000003432712,0.00004338177],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002018948,0.00006513907,0.0005927406,0.000003716525,0.00001671245,3.338806e-7,0.0001413157,0.0001519285,0.9632316,0.0003913085,0.00002852081,0.03535645],"study_design_scores_gemma":[0.0001746846,0.00004647352,0.06556475,0.000003016639,0.00004379311,0.000004828415,0.00001976707,0.0002550168,0.9121422,0.003085971,0.01848659,0.0001729657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996718,0.00005345753,0.0002102668,0.00009473618,0.00001094012,0.00007150288,0.00001279094,0.00002154782,0.002806756],"genre_scores_gemma":[0.999098,0.0001642759,0.0002921764,0.00008460535,0.00001740403,0.000002943664,0.000040489,0.00001224225,0.0002878329],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06497201,"threshold_uncertainty_score":0.9608728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004707506502084105,"score_gpt":0.1839131695077432,"score_spread":0.1792056630056591,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}