{"id":"W2030354188","doi":"10.1039/c2dt32008h","title":"Synthesis and chemistry of bis(triisopropylphosphine) nickel(<scp>i</scp>) and nickel(0) precursors","year":2012,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":93,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Nickel; Yield (engineering); Thermal decomposition; Metathesis; Medicinal chemistry; Carbon disulfide; Benzene; Toluene; Adduct; Solvent; Tetramethylurea; Diphenylphosphine; Nuclear magnetic resonance spectroscopy; Phosphine; Organic chemistry; Polymerization; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001840855,0.0002774681,0.0004374316,0.00007092378,0.0001927673,0.00003624393,0.0001723014,0.0001871182,0.005930701],"category_scores_gemma":[0.0001530791,0.0002693863,0.000172848,0.0002576025,0.000247222,0.0002378796,0.00002292544,0.0002168343,0.00001171331],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003534262,"about_ca_system_score_gemma":0.00003676478,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009672072,"about_ca_topic_score_gemma":0.00001205532,"domain_scores_codex":[0.9985979,0.00001757374,0.000394186,0.0003573059,0.0002342884,0.000398796],"domain_scores_gemma":[0.9984727,0.0005832227,0.0001574673,0.000453418,0.00004644939,0.0002867312],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002732753,0.0009819302,0.007141075,0.001605043,0.000877256,0.000002236412,0.001805727,0.000007588636,0.8933734,0.0002031522,0.0002118761,0.09376343],"study_design_scores_gemma":[0.000269683,0.0000104427,0.001949238,0.00006441782,0.00056132,0.00004316752,0.001694362,0.00008475176,0.9528669,0.00003663402,0.04224309,0.0001759687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824974,0.004521575,0.0007093542,0.0001168768,0.0000482088,0.00007239368,0.0002090731,0.00008385941,0.01174129],"genre_scores_gemma":[0.9905307,0.001121894,0.0003529788,0.00001070139,0.00007853733,0.00005742586,0.00001875636,0.00004425702,0.0077847],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09358746,"threshold_uncertainty_score":0.9999759,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01254669167317383,"score_gpt":0.216851493693561,"score_spread":0.2043048020203871,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}