{"id":"W2030385128","doi":"10.1002/1521-3773(20000915)39:18<3263::aid-anie3263>3.0.co;2-h","title":"Five-Coordinate Carbides in Ti-Al-C Complexes","year":2000,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Carbide; Trigonal bipyramidal molecular geometry; Tetrahedron; Crystallography; Chemistry; Materials science; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001308272,0.000286772,0.0002348325,0.0001821412,0.0003213412,0.0008041074,0.0007356212,0.0003797194,0.002356064],"category_scores_gemma":[0.0002640865,0.0002340423,0.0001151695,0.0001618829,0.0002067711,0.0003564184,0.0003980305,0.0004577078,0.0005608014],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007723637,"about_ca_system_score_gemma":0.0002078875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001149337,"about_ca_topic_score_gemma":0.001862704,"domain_scores_codex":[0.999798,0.00002134873,0.00001566665,0.00005133107,0.00005387382,0.00005987536],"domain_scores_gemma":[0.9999336,0.00001277885,0.00001576428,0.00001075082,0.00001056051,0.0000165797],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004163311,0.00006479688,0.0005059897,0.0001713289,0.00003020404,0.0002306663,0.0002329823,0.001024293,0.9863533,0.005157178,0.0006924559,0.005120457],"study_design_scores_gemma":[0.00009995335,0.0001671766,0.001262289,0.000007391154,0.00002131652,0.000282372,0.00006327077,0.002475827,0.9896833,0.0003852639,0.005530358,0.00002149336],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887511,0.000604441,0.001480435,0.00008304643,0.00002990655,0.00003579304,0.0001389485,0.0001223785,0.008753806],"genre_scores_gemma":[0.9977487,0.0001102786,0.0005970788,0.00002032806,0.000003827019,0.00001386965,0.0001303135,0.00001842821,0.001357084],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002356064,"threshold_uncertainty_score":0.007881761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01207994142527322,"score_gpt":0.2443009424038019,"score_spread":0.2322210009785287,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}