{"id":"W2030502146","doi":"10.1021/tx020058m","title":"Determination of Arsenic Metabolic Complex Excreted in Human Urine after Administration of Sodium 2,3-Dimercapto-1-propane Sulfonate","year":2002,"lang":"en","type":"article","venue":"Chemical Research in Toxicology","topic":"Arsenic contamination and mitigation","field":"Environmental Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Arsenic; Arsenite; Arsenate; Urine; Ternary complex; Nuclear chemistry; Chromatography; Inorganic chemistry; Biochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007308489,0.00009006081,0.0002249513,0.0002220332,0.0000222489,0.000004644547,0.0001951324,0.0001464043,0.004328053],"category_scores_gemma":[0.0003953197,0.00009419995,0.00003785842,0.0005498875,0.0005977548,0.0001182257,0.0001578148,0.0002770385,0.00003500843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001784833,"about_ca_system_score_gemma":0.00002094848,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008086499,"about_ca_topic_score_gemma":0.000434739,"domain_scores_codex":[0.9982653,0.000258502,0.0004853588,0.0002717519,0.0004064344,0.0003126908],"domain_scores_gemma":[0.9994078,0.0001853794,0.0001009228,0.0001865614,0.00004280323,0.00007650091],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008373909,0.000338054,0.003772524,0.00002189211,0.000001916612,0.00001633067,0.0003171775,0.000002492871,0.980119,0.0004266948,0.00005447932,0.01484565],"study_design_scores_gemma":[0.001255992,0.0002448112,0.1602695,0.0000259764,0.000004269385,0.000009184981,0.00008059948,0.0105996,0.8252261,0.001501789,0.0006589321,0.0001232474],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946658,0.00004129488,0.00002089077,0.0005687356,0.00001712798,0.0003128907,0.000004207458,0.000007067885,0.004361977],"genre_scores_gemma":[0.9990739,0.00002879888,0.000457153,0.00003483398,0.00001176964,0.00008005419,0.00002057153,0.000007957141,0.0002849731],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.156497,"threshold_uncertainty_score":0.9965822,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08823917056989294,"score_gpt":0.3629561534618287,"score_spread":0.2747169828919358,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}