{"id":"W2030550077","doi":"10.1021/ja036649w","title":"Phosphine Coordination Complexes of the Diphenylphosphenium Cation:  A Versatile Synthetic Methodology for P−P Bond Formation","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":151,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Phosphine; Combinatorial chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005398205,0.0001253939,0.0004147127,0.00001001679,0.0001233151,0.00001531341,0.0004693628,0.00004806733,0.0004432923],"category_scores_gemma":[0.0007946385,0.00007411224,0.0008630566,0.0003302346,0.0003684265,0.00007958267,0.00006838388,0.0001812407,4.806135e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001750766,"about_ca_system_score_gemma":0.00006908254,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002104365,"about_ca_topic_score_gemma":0.000001256065,"domain_scores_codex":[0.998848,0.0000501063,0.0005250376,0.0001134521,0.0003041136,0.000159285],"domain_scores_gemma":[0.997311,0.0006643166,0.001432164,0.0003267822,0.0002220749,0.00004365567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003488388,0.00008724333,0.0002939078,0.00005418139,0.0001630653,2.832604e-8,0.0005258362,0.00001744929,0.9937662,0.0005470539,0.002097516,0.002412643],"study_design_scores_gemma":[0.0003438354,0.00001908346,0.0004526587,0.00002935215,0.0002712623,0.00002439428,0.001424844,0.0002509772,0.9843218,0.00168196,0.01109041,0.00008940622],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925045,0.0002406399,0.004458862,0.00219868,0.00009089102,0.00008255844,0.00002283218,0.000006540411,0.0003944751],"genre_scores_gemma":[0.9887698,0.00002356201,0.0107713,0.0001692184,0.00007821107,0.000007746286,0.000002589596,0.00001418342,0.0001633566],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009444374,"threshold_uncertainty_score":0.485374,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02517449189636288,"score_gpt":0.2632952379675401,"score_spread":0.2381207460711772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}