{"id":"W2030711986","doi":"10.1021/la100444n","title":"Detection of Hydrogen Peroxide Produced during the Oxygen Reduction Reaction at Self-Assembled Thiol−Porphyrin Monolayers on Gold using SECM and Nanoelectrodes","year":2010,"lang":"en","type":"article","venue":"Langmuir","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Porphyrin; Electrocatalyst; Monolayer; Scanning electrochemical microscopy; Glassy carbon; Chemistry; Cyclic voltammetry; Substrate (aquarium); Electrochemistry; Hydrogen peroxide; Self-assembled monolayer; Photochemistry; Inorganic chemistry; Tetraphenylporphyrin; Electrode; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003972386,0.0005210713,0.0003148645,0.0003677406,0.0001613187,0.0002533,0.0003608545,0.0004436587,0.0005434264],"category_scores_gemma":[0.0004419025,0.0002673227,0.0001767462,0.000332656,0.0002736935,0.0003149816,0.0002386093,0.0003918142,0.0001988313],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002703446,"about_ca_system_score_gemma":0.0001399725,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004247305,"about_ca_topic_score_gemma":0.0005027206,"domain_scores_codex":[0.9997043,0.00007018787,0.00002098185,0.00007359043,0.00009718059,0.00003375149],"domain_scores_gemma":[0.9997781,0.00007945059,0.00004283358,0.00002998684,0.00003823185,0.00003143334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000214569,0.000006738147,0.0001180483,0.00002566943,0.000003159465,0.0000236855,0.00001781478,0.00002548464,0.9990466,0.00003625218,0.000009415613,0.000665536],"study_design_scores_gemma":[0.000003642997,0.00005579934,0.0009455004,0.000001724823,0.000005919516,0.00005009884,0.00001359939,0.0005917744,0.9981235,0.00001974335,0.0001869031,0.000001826004],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895236,0.0007088939,0.008990863,0.00005169532,0.00002403141,0.00002488965,0.0001321532,0.00008773382,0.0004559943],"genre_scores_gemma":[0.9724744,0.001030186,0.02303359,0.00005161364,0.00002979884,0.00007168825,0.0003732124,0.00002656148,0.002908993],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005434264,"threshold_uncertainty_score":0.002100825,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005888200923247233,"score_gpt":0.2112514463280603,"score_spread":0.205363245404813,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}