{"id":"W2030722624","doi":"10.1039/b907737e","title":"Synthesis and solid-state characterization of platinum complexes with hexadentate amino- and iminophosphine ligands","year":2009,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; Université Laval","funders":"","keywords":"Chemistry; Crystallography; Platinum; Nuclear magnetic resonance spectroscopy; Phosphine; Stereochemistry; Spectroscopy; Solid-state nuclear magnetic resonance; Imine; Nuclear magnetic resonance; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002142989,0.0001195255,0.0001675273,0.00004005937,0.0001287412,0.00001848492,0.00004812363,0.00004238683,0.00007555824],"category_scores_gemma":[0.000001957021,0.0001091302,0.00001893824,0.0001085863,0.00008719898,0.0001329333,0.000002532573,0.00008930177,4.350437e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001065214,"about_ca_system_score_gemma":0.000009118588,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000190371,"about_ca_topic_score_gemma":0.00001200576,"domain_scores_codex":[0.9994281,0.000002538695,0.0001885009,0.0001854473,0.00007751007,0.0001178875],"domain_scores_gemma":[0.9996272,0.00003564042,0.00009426946,0.0001477264,0.00003502483,0.00006011346],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004043055,0.0000739345,0.0002612812,0.00005021916,0.00001633562,0.000001081982,0.0002293092,0.00003790379,0.9728954,0.0001583255,0.000002441014,0.02623332],"study_design_scores_gemma":[0.00023753,0.00005252043,0.009202761,0.00006409896,0.00005385076,0.00002559283,0.00006524487,0.000699954,0.9884971,0.0003433007,0.0006189689,0.0001390933],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9154729,0.00002892915,0.08339698,0.0003006223,0.0000029609,0.00009233311,0.0003263727,0.00009978522,0.0002791257],"genre_scores_gemma":[0.9971588,0.0005274715,0.001814829,0.00003376124,0.00001023864,0.00003986554,0.00005646864,0.00001305912,0.0003455675],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08168585,"threshold_uncertainty_score":0.4450201,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01018868749283732,"score_gpt":0.2520448588864909,"score_spread":0.2418561713936536,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}