{"id":"W2030791343","doi":"10.1021/om030594p","title":"Steric Effects on Silene Reactivity. The Effects of<i>o</i><i>rtho</i>-Methyl Substituents on the Kinetics and Mechanisms of the Reactions of 1,1-Diarylsilenes with Nucleophiles","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Reactivity (psychology); Reaction rate constant; Kinetic isotope effect; Nucleophile; Photochemistry; Methanol; Aryl; Acetonitrile; Medicinal chemistry; Steric effects; Deuterium; Kinetics; Stereochemistry; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003578308,0.0004312836,0.0001728186,0.00008714053,0.0001543729,0.0002206369,0.0001857728,0.0002309152,0.002474691],"category_scores_gemma":[0.0004690769,0.0001577825,0.0002341586,0.00007003827,0.0002073818,0.0003460988,0.0001357857,0.0003574269,0.0003677315],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002181081,"about_ca_system_score_gemma":0.0001657521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000412902,"about_ca_topic_score_gemma":0.0007698253,"domain_scores_codex":[0.9998473,0.00003237162,0.00000847488,0.00003142464,0.00003341293,0.00004709756],"domain_scores_gemma":[0.9995877,0.0001911973,0.0001157925,0.00002393721,0.00004750914,0.00003374536],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002616472,0.00001455347,0.0003242669,0.00009376913,0.000009922821,0.0000663295,0.00003570848,0.0002376572,0.9975755,0.0001168686,0.00003773089,0.001226227],"study_design_scores_gemma":[0.00001229755,0.0005392813,0.002795534,0.00000645093,0.00001725427,0.0001155436,0.00002615464,0.0009877556,0.9946056,0.00003241315,0.0008525593,0.000009072942],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935669,0.001584774,0.001058521,0.00006119412,0.00002057306,0.00002165228,0.0001928266,0.00004777366,0.003445679],"genre_scores_gemma":[0.9973846,0.0007670347,0.0005574079,0.00003158177,0.000007932712,0.00001354162,0.0001705997,0.000014012,0.001053177],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002474691,"threshold_uncertainty_score":0.008278668,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007930474619751472,"score_gpt":0.1876981907633983,"score_spread":0.1797677161436468,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}