{"id":"W2030822551","doi":"10.1016/j.tet.2005.04.024","title":"Reactions of allyloxy(methoxy)carbene in solution. Carbene rearrangement and Claisen rearrangement of the carbene dimer","year":2005,"lang":"en","type":"article","venue":"Tetrahedron","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Carbene; Chemistry; Claisen rearrangement; Dimer; Carroll rearrangement; Cope rearrangement; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002080802,0.0004094747,0.0003842719,0.0002698041,0.000428075,0.0003617797,0.0004476919,0.0005253482,0.003497652],"category_scores_gemma":[0.0002627316,0.0002181979,0.0002029637,0.0002489625,0.0003386798,0.0007383871,0.000370471,0.001098639,0.0005807703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004382795,"about_ca_system_score_gemma":0.0002797422,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00124454,"about_ca_topic_score_gemma":0.002000139,"domain_scores_codex":[0.9997289,0.00003599781,0.000008621747,0.00007785939,0.00005188058,0.00009680715],"domain_scores_gemma":[0.9999288,0.00002614457,0.0000124382,0.000008205253,0.000006944766,0.00001747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000409367,0.00006364664,0.00009628941,0.0002047848,0.00003046916,0.0001752483,0.0002727626,0.000624122,0.9880543,0.002377674,0.0008798623,0.006811426],"study_design_scores_gemma":[0.0001139539,0.0003818545,0.0003443892,0.00002254325,0.00001803999,0.0001958787,0.00007526676,0.001017505,0.9913805,0.0005527416,0.005877573,0.00001973432],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9196678,0.01582328,0.008835741,0.0006372159,0.0002425128,0.0001120459,0.0003579857,0.0001523041,0.0541712],"genre_scores_gemma":[0.9867055,0.002762029,0.001219413,0.0001003226,0.0000235772,0.00002844325,0.0002206847,0.00002017821,0.008919965],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003497652,"threshold_uncertainty_score":0.01170087,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009318081920309805,"score_gpt":0.2309811389799068,"score_spread":0.221663057059597,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}