{"id":"W2030894031","doi":"10.1021/ja401492s","title":"Stoichiometric Metal-Free Reduction of CO in Syn-Gas","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":163,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Stoichiometry; Borane; Derivative (finance); Boron; Bond cleavage; Metal; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002003795,0.0001663821,0.000492668,0.00004338111,0.00003386089,0.00001897794,0.0008673199,0.0001064801,0.0009096872],"category_scores_gemma":[0.0004372848,0.0001167814,0.0005824594,0.0009514113,0.0004971314,0.0001281518,0.0001644158,0.0006642705,0.000007708999],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002732541,"about_ca_system_score_gemma":0.0001024721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000886304,"about_ca_topic_score_gemma":2.525497e-7,"domain_scores_codex":[0.9984413,0.00002396098,0.0006389462,0.0001566269,0.0004902475,0.0002488857],"domain_scores_gemma":[0.9980537,0.0001274816,0.001080965,0.000458993,0.0001559267,0.0001229307],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001953472,0.0001749854,0.004888302,0.00005475937,0.0001023412,7.088952e-7,0.0001763288,0.000003705105,0.9815401,0.000002027546,0.01102379,0.002013348],"study_design_scores_gemma":[0.0007608261,0.00001935325,0.001883049,0.00004411914,0.000051001,0.00009064876,0.001104447,0.00002464794,0.9953691,0.0001786766,0.0003504304,0.0001236608],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975882,0.0001815628,0.000003958525,0.001331253,0.00007488943,0.00003863365,0.000007350132,0.00001172442,0.0007624642],"genre_scores_gemma":[0.9983954,0.0001706763,0.0008669962,0.0001535755,0.0002563962,0.000002580155,0.000001187203,0.00002298804,0.0001301693],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01382897,"threshold_uncertainty_score":0.9960437,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00837777306058986,"score_gpt":0.2398105422906902,"score_spread":0.2314327692301004,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}