{"id":"W2031033767","doi":"10.1016/j.hydromet.2003.07.010","title":"Pressure oxidation of pyrite in sulfuric acid media: a kinetic study","year":2003,"lang":"en","type":"article","venue":"Hydrometallurgy","topic":"Metal Extraction and Bioleaching","field":"Engineering","cited_by":109,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Barrick Gold Corporation","keywords":"Chemistry; Pyrite; Sulfuric acid; Thiosulfate; Inorganic chemistry; Partial pressure; Sulfur; Oxygen; Passivation; Disproportionation; Order of reaction; Activation energy; Sulfate; Reaction rate; Catalysis; Redox; Kinetics; Mineralogy; Reaction rate constant; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003036877,0.0003047983,0.0003879819,0.0002221068,0.000272293,0.0004217333,0.0005975099,0.0003736617,0.0009512885],"category_scores_gemma":[0.0004050943,0.0001846382,0.0003274166,0.0002946943,0.000325786,0.0007325952,0.0002338652,0.000508677,0.0003663535],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004373711,"about_ca_system_score_gemma":0.0002904703,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003862606,"about_ca_topic_score_gemma":0.00235394,"domain_scores_codex":[0.9997756,0.00003274948,0.00001345683,0.00003995432,0.00008680973,0.00005142889],"domain_scores_gemma":[0.9997894,0.00008229566,0.00002412081,0.00002034421,0.00006799516,0.00001586805],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006925368,0.0001935259,0.00105401,0.0001628275,0.00003782985,0.0001342945,0.0001765623,0.0007502318,0.9875858,0.0006279389,0.0001666324,0.00841793],"study_design_scores_gemma":[0.00002369759,0.0006234939,0.004051824,0.000008760135,0.00002585837,0.0001948287,0.0001263006,0.006669493,0.9863729,0.0001513722,0.001731908,0.00001938305],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938477,0.00104774,0.003032612,0.0000643765,0.0000153003,0.00002130166,0.0001552547,0.00002420874,0.001791649],"genre_scores_gemma":[0.9963267,0.0006928235,0.0009180161,0.000008337964,0.000006931849,0.000008315285,0.0002329995,0.00000899951,0.001796879],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003862606,"threshold_uncertainty_score":0.007680297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01156520571021281,"score_gpt":0.2121977515181423,"score_spread":0.2006325458079295,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}