{"id":"W2031453151","doi":"10.1021/ol701742x","title":"Stereoselective Syntheses of 4-Oxa Diaminopimelic Acid and Its Protected Derivatives via Aziridine Ring Opening","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Heritage Foundation for Medical Research","keywords":"Aziridine; Chemistry; Diaminopimelic acid; Stereoselectivity; Ring (chemistry); Stereochemistry; Combinatorial chemistry; Organic chemistry; Catalysis; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002171223,0.0004693985,0.0002926518,0.0002044231,0.0001291673,0.0002393238,0.0003756251,0.0002792219,0.001180666],"category_scores_gemma":[0.0001854619,0.0002222355,0.0002411564,0.0002138871,0.0001927221,0.0003426421,0.0002518138,0.0005603023,0.0005159727],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002668473,"about_ca_system_score_gemma":0.0002830434,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002381915,"about_ca_topic_score_gemma":0.0003316714,"domain_scores_codex":[0.9998728,0.00001775732,0.00001421663,0.00002791116,0.00003215743,0.00003518553],"domain_scores_gemma":[0.9999008,0.00001188374,0.00003376082,0.00001519023,0.00001597679,0.00002238074],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009311219,0.00002557632,0.0000511573,0.00006963546,0.000008287443,0.0001699501,0.00003907261,0.0002799746,0.9943849,0.0006651678,0.00004721609,0.00416611],"study_design_scores_gemma":[0.00001895287,0.0002532748,0.0002438182,0.000002730097,0.00001015113,0.0001766547,0.00001130052,0.0003875465,0.9957644,0.0001077886,0.003015331,0.000008046778],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9530213,0.003892003,0.030237,0.0001483924,0.0001397406,0.0001498706,0.0006504055,0.0002007634,0.01156046],"genre_scores_gemma":[0.9757789,0.002397714,0.01772261,0.00003267358,0.00002359507,0.00005366791,0.0003702955,0.00003577536,0.003584729],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001180666,"threshold_uncertainty_score":0.003949761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01637591742969281,"score_gpt":0.230932653672721,"score_spread":0.2145567362430282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}