{"id":"W2031534892","doi":"10.1021/jo049603+","title":"Generation and Absolute Reactivity of an Aryl Enol Radical Cation in Solution","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Enol; Photochemistry; Radical ion; Deprotonation; Flash photolysis; Acetonitrile; Reactivity (psychology); Reaction rate constant; Nucleophile; Medicinal chemistry; Organic chemistry; Catalysis; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001665638,0.0002673449,0.0001457081,0.00009367575,0.0001256456,0.0002880212,0.0002252548,0.0003395613,0.0009503763],"category_scores_gemma":[0.000328861,0.00009123698,0.00009458863,0.00008019982,0.0002132705,0.0002758369,0.0001497217,0.0003224341,0.000301553],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002716558,"about_ca_system_score_gemma":0.0001526206,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005271801,"about_ca_topic_score_gemma":0.0005740008,"domain_scores_codex":[0.9998819,0.0000160127,0.000004637214,0.00003244005,0.00003468094,0.00003036292],"domain_scores_gemma":[0.999876,0.00004458576,0.00002743657,0.000008816735,0.0000257416,0.00001735202],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003871975,0.000002695368,0.00008215816,0.00001962693,0.000001897219,0.00001529543,0.000009023389,0.00004829203,0.9989476,0.00005130908,0.00000993393,0.0007735351],"study_design_scores_gemma":[0.000005953108,0.0001109039,0.0005089264,0.000001744927,0.000004472769,0.00006416164,0.00001176585,0.0003128228,0.998384,0.0000306722,0.0005617572,0.000002787953],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993252,0.002225966,0.002991329,0.00004861319,0.00001851303,0.00001039371,0.00009764606,0.00003197509,0.001323689],"genre_scores_gemma":[0.9953694,0.0008767502,0.001712895,0.00002072537,0.000007769999,0.00001257909,0.0001810257,0.0000078884,0.001811057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009503763,"threshold_uncertainty_score":0.003179312,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01533237184770194,"score_gpt":0.2365453391060875,"score_spread":0.2212129672583856,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}