{"id":"W2031946431","doi":"10.1039/c1cc12125a","title":"Covalent diamond–gold nanojewel hybrids via photochemically generated carbenes","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Diamond and Carbon-based Materials Research","field":"Materials Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Covalent bond; Chemistry; Carbene; Combinatorial chemistry; Diamond; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004081553,0.0002437069,0.000311085,0.00007295223,0.0001736744,0.0001055055,0.002234733,0.0001520746,0.0009539707],"category_scores_gemma":[0.000164479,0.0002242578,0.0001183587,0.0002821679,0.0006137146,0.0001520428,0.0009561641,0.0002545154,0.0004541939],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009469238,"about_ca_system_score_gemma":0.0001361809,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003819186,"about_ca_topic_score_gemma":0.00001487068,"domain_scores_codex":[0.9980465,0.0001816494,0.0004819535,0.0004116189,0.0003525484,0.0005257729],"domain_scores_gemma":[0.9969358,0.0001657483,0.0001155554,0.002223784,0.0002707416,0.0002883158],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003630528,0.0003378383,0.0001228293,0.00002614687,0.00001242138,0.000003243864,0.0001975303,5.853022e-7,0.9969773,0.0005929026,0.001168795,0.0005241183],"study_design_scores_gemma":[0.0003166422,0.00003130812,0.00009161162,0.00002959466,0.00002626341,0.000007958012,0.00003031777,0.0003127403,0.9947897,0.00126385,0.002818079,0.0002819943],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821833,0.0007069561,0.0001817883,0.00024442,0.0001604238,0.0003436999,0.0001003875,0.0002542855,0.01582476],"genre_scores_gemma":[0.9903429,0.0001924424,0.008248607,0.000269086,0.00007723117,0.0003791159,0.0001850262,0.00004240195,0.0002631831],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01556158,"threshold_uncertainty_score":0.9999593,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06113996368936334,"score_gpt":0.2831068098913354,"score_spread":0.2219668462019721,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}