{"id":"W2031957876","doi":"10.1021/cr100388p","title":"Reactivity by Design—Metallaoxetanes as Centerpieces in Reaction Development","year":2011,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Reactivity (psychology); Combinatorial chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001488389,0.0008162304,0.0003457893,0.0008384634,0.0006038495,0.001311821,0.001079177,0.0006247215,0.08367951],"category_scores_gemma":[0.001757017,0.0005376642,0.0004606569,0.0008072527,0.000519544,0.002422471,0.001682758,0.001548238,0.02497562],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001072722,"about_ca_system_score_gemma":0.000661525,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000632067,"about_ca_topic_score_gemma":0.001729248,"domain_scores_codex":[0.9989936,0.0001663388,0.00004340884,0.0001198959,0.0005664842,0.000110218],"domain_scores_gemma":[0.9993089,0.0001396205,0.00009975938,0.0001430651,0.0001866632,0.0001219741],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0005296048,0.0003079987,0.001927443,0.001856959,0.00004505561,0.000281826,0.0004631439,0.001022017,0.07262187,0.1048455,0.2803666,0.535732],"study_design_scores_gemma":[0.00004097994,0.0003981566,0.001208861,0.0001564111,0.00002731071,0.0002754567,0.0001322942,0.001265335,0.08681937,0.01106712,0.898574,0.00003473004],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"review","genre_scores_codex":[0.05370506,0.0412894,0.1126519,0.01613561,0.006058687,0.001030572,0.004777991,0.01020936,0.7541414],"genre_scores_gemma":[0.3339956,0.04679682,0.09550918,0.00324112,0.001258075,0.000953819,0.006594183,0.004116211,0.507535],"genre_candidate":"review","genre_consensus":null,"teacher_disagreement_score":0.08367951,"threshold_uncertainty_score":0.2799358,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09361242432825048,"score_gpt":0.328647603929662,"score_spread":0.2350351796014115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}