{"id":"W2031957876","doi":"10.1021/cr100388p","title":"Reactivity by Design—Metallaoxetanes as Centerpieces in Reaction Development","year":2011,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Reactivity (psychology); Combinatorial chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008636604,0.0008494279,0.003284564,0.0002412995,0.00002500311,0.00003413166,0.0006540538,0.0006696802,0.0003622522],"category_scores_gemma":[0.001662376,0.0007200811,0.0007813444,0.0008859711,0.00005995722,0.0001761716,0.0002114718,0.0008541772,0.00120171],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009125192,"about_ca_system_score_gemma":0.0001587995,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003185078,"about_ca_topic_score_gemma":0.000002868683,"domain_scores_codex":[0.9959683,0.0001886036,0.002032915,0.0009756468,0.000319181,0.0005153127],"domain_scores_gemma":[0.997675,0.0004089485,0.0007901932,0.0008283671,0.00004802173,0.0002494568],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000006299292,0.0001257546,5.285681e-7,0.009911371,0.00008879884,0.000005999452,0.00004516627,1.531871e-7,0.005777526,0.00002545348,0.001567616,0.9824454],"study_design_scores_gemma":[0.0001053718,0.000003986408,6.934216e-8,0.01044907,0.0003780337,0.00002998663,0.000001893654,0.00001172534,0.0140312,0.00001634667,0.9743249,0.0006474206],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.00002199419,0.9951554,0.0009892172,0.000004084257,0.0001581075,0.001136649,0.00001005831,0.0001424986,0.002382013],"genre_scores_gemma":[0.00001399434,0.9961563,0.001332832,0.00002900188,0.00008887526,0.0008494122,0.000545003,0.0001254232,0.0008591103],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9817979,"threshold_uncertainty_score":0.999576,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09361242432825048,"score_gpt":0.328647603929662,"score_spread":0.2350351796014115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}