{"id":"W2032017745","doi":"10.1021/ja049538l","title":"Biomimetic Monoacylation of Diols in Water. Lanthanide-Promoted Reactions of Methyl Benzoyl Phosphate","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Lanthanide; Phosphate; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002452148,0.0001370349,0.0004984908,0.00002582954,0.00003927979,0.000007593826,0.0003309071,0.00009787681,0.00009993713],"category_scores_gemma":[0.0001806949,0.00008125827,0.0006842802,0.0003266917,0.0003593022,0.00007877972,0.00008216508,0.000418593,9.693221e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002596062,"about_ca_system_score_gemma":0.00005940887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004476999,"about_ca_topic_score_gemma":0.000002154079,"domain_scores_codex":[0.9985538,0.00001848363,0.0007783074,0.0001308381,0.0003131618,0.0002054145],"domain_scores_gemma":[0.9983753,0.0001856354,0.00100113,0.0002410685,0.0001170615,0.00007980983],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005049428,0.0003158357,0.0009598674,0.00005778571,0.0001401629,6.724283e-7,0.0002841078,0.0001495742,0.9958869,0.000009981583,0.00003413741,0.002110495],"study_design_scores_gemma":[0.000550269,0.00002269919,0.0005414237,0.0001972802,0.00009720713,0.00002274744,0.0004059276,0.00007171635,0.9968398,0.0008670463,0.00028686,0.00009703299],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986026,0.0001177257,0.00006425257,0.0008720623,0.00004043501,0.00003276527,0.00001143012,0.00000808435,0.0002507023],"genre_scores_gemma":[0.9979137,0.0002458425,0.00167795,0.00002642367,0.00008600422,0.000002175129,0.000003067805,0.00001584336,0.00002895094],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002013462,"threshold_uncertainty_score":0.3313616,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01130495439233332,"score_gpt":0.2485744583385963,"score_spread":0.237269503946263,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}