{"id":"W2032031082","doi":"10.1021/ma021109p","title":"Arborescent Polystyrene-<i>g</i><i>raft</i>-poly(2-vinylpyridine) Copolymers as Unimolecular Micelles. Synthesis from Acetylated Substrates","year":2003,"lang":"en","type":"article","venue":"Macromolecules","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Copolymer; Polymer chemistry; Polystyrene; Side chain; Branching (polymer chemistry); Micelle; Raft; Tetrahydrofuran; Chemistry; Molar mass distribution; Grafting; Aqueous solution; Yield (engineering); Reactivity (psychology); Polymer; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0003369972,0.0007041783,0.0007113588,0.0001939375,0.0003804094,0.0003584147,0.0007792066,0.0002932867,0.005232746],"category_scores_gemma":[0.0001875374,0.0006831955,0.0003276709,0.0004905112,0.0004762002,0.0002048399,0.0001200397,0.0002808413,0.001872013],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001002059,"about_ca_system_score_gemma":0.0002963205,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003345015,"about_ca_topic_score_gemma":0.0001732097,"domain_scores_codex":[0.9959066,0.0004350784,0.0006733618,0.001110266,0.0007054611,0.001169255],"domain_scores_gemma":[0.9979252,0.0002328917,0.0002808087,0.000951644,0.00009397719,0.0005154959],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009902235,0.0001805492,0.0004707252,0.0000212932,0.0001166594,0.0003346259,0.0003177391,0.00001632445,0.9949706,0.00201878,0.0008105258,0.0006431675],"study_design_scores_gemma":[0.000789265,0.00007217789,0.0002317267,0.00008906735,0.0002112586,0.0000525384,0.0004386527,0.00003463904,0.9861263,0.0003301435,0.0107995,0.0008247441],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.964675,0.01649196,0.0002420956,0.0004156437,0.0009678172,0.0003117006,0.0002199707,0.000315183,0.0163606],"genre_scores_gemma":[0.9966156,0.0002365304,0.001417782,0.0008222702,0.0001058199,0.00005807444,0.00006005907,0.0001376853,0.00054611],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03194064,"threshold_uncertainty_score":0.9995619,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007858972531616583,"score_gpt":0.2161180264704048,"score_spread":0.2082590539387882,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}