{"id":"W2032567452","doi":"10.1021/jp204969d","title":"Pulsed ENDOR Determination of Relative Orientation of <i>g</i>-Frame and Molecular Frame of Imidazole-Coordinated Heme Center of iNOS","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"National Center for Research Resources; National Institute of General Medical Sciences; National Heart, Lung, and Blood Institute; National Institutes of Health","keywords":"Heme; Chemistry; Electron paramagnetic resonance; Imidazole; Nitric oxide synthase; Crystallography; Hemeprotein; Stereochemistry; Nuclear magnetic resonance; Photochemistry; Nitric oxide; Physics; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001668862,0.0001490205,0.0001206501,0.00008258697,0.0001246055,0.0001560081,0.0002528696,0.0001656086,0.0004965953],"category_scores_gemma":[0.0003016186,0.0001208071,0.00006274501,0.00009965311,0.0002487131,0.0001915825,0.0001034362,0.0003183575,0.0001141603],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003929192,"about_ca_system_score_gemma":0.0001497841,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001088601,"about_ca_topic_score_gemma":0.001105876,"domain_scores_codex":[0.9999623,0.000005406007,0.000001463996,0.0000127617,0.00001139161,0.000006583299],"domain_scores_gemma":[0.99991,0.00002337437,0.00002859969,0.000007033831,0.00001979834,0.0000112257],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002736097,0.00004196056,0.00320763,0.00007579064,0.000008873928,0.0001619279,0.0001362867,0.01052138,0.9780989,0.00245656,0.0001880199,0.004829053],"study_design_scores_gemma":[0.00003747929,0.0002106812,0.01094514,0.00001708921,0.00002123663,0.0001523699,0.0002330612,0.2440482,0.7416394,0.0008588619,0.001799596,0.0000369161],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870782,0.0001315179,0.01149235,0.00003620344,0.000009136429,0.000007342083,0.0000760622,0.00003947267,0.001129707],"genre_scores_gemma":[0.9953642,0.0000843505,0.004293167,0.000008678742,0.000001316236,0.000005196354,0.000070888,0.00001346896,0.0001587923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001088601,"threshold_uncertainty_score":0.002850831,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007950421863377324,"score_gpt":0.2467534260169956,"score_spread":0.2388030041536183,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}