{"id":"W2032704980","doi":"10.1021/ic000623d","title":"Syntheses, Structures, and Luminescence of Novel Lanthanide Complexes of Tripyridylamine, <i>N,N,N</i><i>‘</i><i>,N</i><i>‘</i>-Tetra(2-pyridyl)-1,4-phenylenediamine and <i>N,N,N</i><i>‘</i><i>,N</i><i>‘</i>-Tetra(2-pyridyl)biphenyl-4,4‘-diamine","year":2000,"lang":"he","type":"article","venue":"Inorganic Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; Queen's University","funders":"","keywords":"Chemistry; Lanthanide; Luminescence; Tetra; Photoluminescence; Biphenyl; Diamine; Crystallography; Medicinal chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001413698,0.0002781821,0.0002465161,0.0001155204,0.0002001606,0.0003746131,0.0005454976,0.000294848,0.0008486903],"category_scores_gemma":[0.0002111809,0.000237764,0.0001547955,0.0001373347,0.0001901889,0.0003770706,0.000230503,0.0003760228,0.0002771671],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008059838,"about_ca_system_score_gemma":0.0004343441,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001062727,"about_ca_topic_score_gemma":0.001653763,"domain_scores_codex":[0.9999124,0.000009091596,0.000007747793,0.00002551959,0.00002767482,0.00001759327],"domain_scores_gemma":[0.9998943,0.0000145796,0.00003174214,0.00001307082,0.00002072302,0.00002562458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002859083,0.00001431465,0.00004512397,0.00005824619,0.000004321933,0.00003072252,0.00002771906,0.000153762,0.9979735,0.0002958945,0.00003952061,0.001328454],"study_design_scores_gemma":[0.00002011793,0.00005785833,0.0002180215,0.000002491532,0.000008008285,0.00008409646,0.000007899059,0.0007066558,0.9967067,0.00002247451,0.002161311,0.000004434284],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9807832,0.002232324,0.01303465,0.0001505076,0.00003283792,0.00009394537,0.0002382808,0.0001350846,0.00329924],"genre_scores_gemma":[0.9658887,0.001826381,0.02316938,0.0001024184,0.00001196634,0.0001458647,0.0005912249,0.00008729804,0.008176723],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001062727,"threshold_uncertainty_score":0.005847871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01506547024298603,"score_gpt":0.2218231453000407,"score_spread":0.2067576750570546,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}