{"id":"W2032704980","doi":"10.1021/ic000623d","title":"Syntheses, Structures, and Luminescence of Novel Lanthanide Complexes of Tripyridylamine, <i>N,N,N</i><i>‘</i><i>,N</i><i>‘</i>-Tetra(2-pyridyl)-1,4-phenylenediamine and <i>N,N,N</i><i>‘</i><i>,N</i><i>‘</i>-Tetra(2-pyridyl)biphenyl-4,4‘-diamine","year":2000,"lang":"he","type":"article","venue":"Inorganic Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; Queen's University","funders":"","keywords":"Chemistry; Lanthanide; Luminescence; Tetra; Photoluminescence; Biphenyl; Diamine; Crystallography; Medicinal chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001762852,0.002776938,0.004594697,0.0004370112,0.0006840227,0.0004278936,0.002370227,0.001311486,0.009832839],"category_scores_gemma":[0.0008928356,0.002762483,0.0007461842,0.002065802,0.004637935,0.001284787,0.000862358,0.001447558,0.00007071148],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001708751,"about_ca_system_score_gemma":0.0007584891,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001942368,"about_ca_topic_score_gemma":0.0002086119,"domain_scores_codex":[0.9861938,0.0004584946,0.004847095,0.003440598,0.002500207,0.002559799],"domain_scores_gemma":[0.9902052,0.002426,0.002228273,0.002804053,0.0009211185,0.001415327],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001145543,0.0016149,0.001842531,0.00648142,0.0005009549,0.000127733,0.001306654,0.00004703354,0.9823771,0.0005798196,0.0009234498,0.003052821],"study_design_scores_gemma":[0.006524007,0.000697369,0.00277593,0.002089949,0.001405395,0.001670424,0.001009222,0.0004349443,0.972481,0.0006106663,0.007558548,0.002742612],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9649672,0.01887923,0.0007708691,0.000613053,0.0009383005,0.001620797,0.007962953,0.0003772253,0.003870394],"genre_scores_gemma":[0.9789932,0.01124895,0.005875213,0.0005833726,0.001034748,0.00006699857,0.0004239717,0.0004111673,0.001362374],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01402603,"threshold_uncertainty_score":0.999985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01506547024298603,"score_gpt":0.2218231453000407,"score_spread":0.2067576750570546,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}