{"id":"W2032915884","doi":"10.1002/1521-3900(200208)184:1<1::aid-masy1>3.0.co;2-o","title":"New insights into the development of ordered structure in poly(ethylene terephthalate), II Results from transmission infrared spectroscopy of thin films","year":2002,"lang":"en","type":"article","venue":"Macromolecular Symposia","topic":"Polymer crystallization and properties","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Conformational isomerism; Crystallinity; Materials science; Infrared spectroscopy; Amorphous solid; Infrared; Spectroscopy; Reflection (computer programming); Attenuated total reflection; Crystallography; Ethylene glycol; Phase (matter); Fourier transform infrared spectroscopy; Molecular vibration; Optics; Molecule; Chemistry; Organic chemistry; Composite material; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001321404,0.0002113938,0.0002980037,0.00010394,0.0001402395,0.00003923952,0.0004648597,0.0001272436,0.001173907],"category_scores_gemma":[0.00003135877,0.0001433071,0.00005419502,0.0003118611,0.00008338522,0.0001127953,0.0001173775,0.0001166508,0.000007246123],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003144522,"about_ca_system_score_gemma":0.0001202179,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007298435,"about_ca_topic_score_gemma":0.0001785702,"domain_scores_codex":[0.9981248,0.0001723324,0.000749911,0.0003393829,0.000391352,0.0002222483],"domain_scores_gemma":[0.9991645,0.00003275177,0.000237606,0.0004336249,0.00004518591,0.00008639393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000149315,0.00005018701,0.00003478823,0.00002114116,0.00001634571,0.000007836685,0.0586089,0.0001028814,0.9390943,0.00006057475,0.0001161291,0.001737573],"study_design_scores_gemma":[0.001052299,0.00008497605,0.0006435137,0.0001595313,0.000012143,0.00000238981,0.0001686832,0.0006198686,0.9931167,0.0008879531,0.003077232,0.0001747249],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.98914,0.005363019,0.003343177,0.0002650327,0.0001182966,0.0002361782,0.000027259,0.00003029506,0.001476788],"genre_scores_gemma":[0.9722293,0.00007633156,0.02710572,0.00007707351,0.00001464348,0.000003814474,0.00004451504,0.00002078884,0.0004277858],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05844022,"threshold_uncertainty_score":0.9997392,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0097682990897039,"score_gpt":0.2145017979224275,"score_spread":0.2047334988327236,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}