{"id":"W2033226055","doi":"10.1021/ic0701559","title":"Chemistry and Stereochemistry of the Interaction of the Water-Soluble Phosphine [HO(CH<sub>2</sub>)<sub>3</sub>]<sub>3</sub>P with Cinnamaldehyde in Aqueous Media","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Cinnamaldehyde; Phosphine; Aqueous solution; Aqueous medium; Water soluble; Organic chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007462676,0.001249358,0.00127238,0.00005997248,0.0003001128,0.0001207228,0.001815543,0.001170783,0.0002782157],"category_scores_gemma":[0.0005636545,0.0008882089,0.0004288172,0.0009463973,0.00103552,0.0002906402,0.001247448,0.002098758,0.00001909142],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009827,"about_ca_system_score_gemma":0.0005476258,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001191344,"about_ca_topic_score_gemma":0.0002489042,"domain_scores_codex":[0.9937012,0.00005732127,0.001912573,0.001511226,0.001394737,0.001422972],"domain_scores_gemma":[0.9945372,0.0006383483,0.001288989,0.002693173,0.0004225094,0.0004197813],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005074782,0.0005862434,0.01061899,0.001984408,0.0002772843,0.00007048639,0.0009695094,0.00002022384,0.9803636,0.000001006249,0.000234139,0.004366647],"study_design_scores_gemma":[0.002088079,0.00002498593,0.001751402,0.001232383,0.0002795746,0.0006744248,0.001255506,0.0000868551,0.9912513,0.0001076407,0.0001948099,0.001053003],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961197,0.000785988,0.00001464598,0.0003789571,0.0003179654,0.0003262268,0.0001350951,0.0001864435,0.00173501],"genre_scores_gemma":[0.9985267,0.0003189907,0.00004718888,0.00008740433,0.0004463019,0.00004746814,0.0001038799,0.0002732725,0.0001487788],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01088776,"threshold_uncertainty_score":0.9993569,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004668194759835735,"score_gpt":0.1810294523841536,"score_spread":0.1763612576243178,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}