{"id":"W2033417272","doi":"10.1021/jp063873+","title":"Experimental and Theoretical Studies of the Reaction of the OH Radical with Alkyl Sulfides:  1. Direct Observations of the Formation of the OH−DMS Adduct−Pressure Dependence of the Forward Rate of Addition and Development of a Predictive Expression at Low Temperature","year":2006,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Adduct; Reaction rate constant; Isotopomers; Enthalpy; Physical chemistry; Alkyl; Equilibrium constant; Ab initio; Dissociation (chemistry); Kinetics; Thermodynamics; Analytical Chemistry (journal); Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001079465,0.00086033,0.0003903159,0.0004860332,0.0004975257,0.0002125622,0.001162231,0.0005861153,0.002476878],"category_scores_gemma":[0.002083527,0.0003419524,0.0004616809,0.0004051412,0.0006574675,0.0007132507,0.0004154825,0.0007960223,0.0004225427],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008917587,"about_ca_system_score_gemma":0.0003127911,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002361606,"about_ca_topic_score_gemma":0.0009804351,"domain_scores_codex":[0.9995797,0.00006978415,0.0000181293,0.00006533838,0.0002102169,0.00005686993],"domain_scores_gemma":[0.999167,0.0005446721,0.00008519505,0.00007174293,0.0001107203,0.00002072968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003526723,0.000200155,0.002988007,0.0009326407,0.00004252492,0.0002059068,0.0001981407,0.02957357,0.9497907,0.005158008,0.0001367555,0.01042094],"study_design_scores_gemma":[0.00002823475,0.0004492551,0.004192401,0.00001133367,0.00001958883,0.0001707955,0.00004590204,0.05425136,0.9381494,0.00121164,0.001445072,0.00002508639],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9658229,0.002016424,0.02746559,0.0001444293,0.00001708866,0.00008943813,0.0004962788,0.0001452075,0.003802675],"genre_scores_gemma":[0.9833786,0.002662523,0.01225325,0.0000217499,0.0000412451,0.0001279781,0.000497311,0.00002560102,0.0009917459],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002476878,"threshold_uncertainty_score":0.00828594,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008399793704715077,"score_gpt":0.2054545703813935,"score_spread":0.1970547766766784,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}