{"id":"W2033483517","doi":"10.1016/j.jmr.2009.11.002","title":"Pulse FT NMR of non-equilibrium states of half-integer spin quadrupolar nuclei in single crystals","year":2009,"lang":"en","type":"article","venue":"Journal of Magnetic Resonance","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"University of Alberta; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Government of Canada","keywords":"Single crystal; Spin (aerodynamics); Flip angle; Chemistry; Density matrix; Population; Atomic physics; Molecular physics; Excitation; Half-integer; Condensed matter physics; Physics; Crystallography; Quantum; Thermodynamics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003094226,0.0001343773,0.0003035789,0.0002225035,0.0005445998,0.0006119247,0.0007438294,0.0003807728,0.001600406],"category_scores_gemma":[0.0008004569,0.0003376572,0.00008933681,0.0003772776,0.0005331442,0.0007115195,0.0002534486,0.0009998669,0.0001242527],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006480894,"about_ca_system_score_gemma":0.0005176688,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00320546,"about_ca_topic_score_gemma":0.004816376,"domain_scores_codex":[0.9998272,0.00001807998,0.000008551537,0.00003991891,0.00006911321,0.00003709539],"domain_scores_gemma":[0.99964,0.000175856,0.00004737937,0.0000323796,0.00006662911,0.00003773794],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005310398,0.00008859573,0.001168536,0.0001549518,0.00002114698,0.000228368,0.0003641814,0.001422719,0.9835297,0.004380778,0.0007831027,0.007326858],"study_design_scores_gemma":[0.00006351397,0.0001763224,0.004521171,0.00001973208,0.00001671356,0.0001393715,0.0002057007,0.01990765,0.9723651,0.001052855,0.001507505,0.00002446159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935874,0.0004570721,0.003148935,0.0001018503,0.00002570952,0.000008033276,0.0001543893,0.00004422501,0.002472371],"genre_scores_gemma":[0.9954796,0.0003125091,0.002349505,0.00003589119,0.00001313629,0.00001463841,0.0002015737,0.0000254818,0.001567611],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00320546,"threshold_uncertainty_score":0.006373584,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00993385753084576,"score_gpt":0.2725006498073486,"score_spread":0.2625667922765028,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}