{"id":"W2033490766","doi":"10.1021/ic801625z","title":"Gas-Phase Reactions of Sulfur Hexafluoride with Transition Metal and Main Group Atomic Cations: Room-Temperature Kinetics and Periodicities in Reactivity","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Reactivity (psychology); Sulfur hexafluoride; Kinetics; Gas phase; Sulfur; Transition metal; Inorganic chemistry; Group (periodic table); Metal; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008218212,0.0001148306,0.0001663841,0.000008895567,0.00006379638,0.00002808739,0.00004347211,0.00007959324,0.0001802766],"category_scores_gemma":[0.00001333598,0.0001001336,0.00001582412,0.0001594103,0.00008749236,0.0001620638,0.000002858142,0.0001537536,8.854685e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009655625,"about_ca_system_score_gemma":0.00003354727,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006157761,"about_ca_topic_score_gemma":0.0008096856,"domain_scores_codex":[0.999392,0.00001787575,0.0001683883,0.0001848139,0.0001003489,0.000136606],"domain_scores_gemma":[0.9997044,0.00004107715,0.00006392043,0.0001120225,0.00001698319,0.00006156864],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0001094445,0.00009805044,0.009452938,0.00007720715,0.00001306673,0.00002156221,0.0008263882,0.00002676695,0.9864546,0.000008279868,0.00001463452,0.002897084],"study_design_scores_gemma":[0.002945584,0.0006356099,0.498998,0.0001840475,0.0001416926,0.0009321097,0.007412934,0.0008995191,0.4861709,0.0008444511,0.0002788402,0.0005563189],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985228,0.0006564416,0.00001749738,0.0002786546,0.0000116355,0.00007133988,0.00009228002,0.00001656037,0.000332773],"genre_scores_gemma":[0.9991655,0.0003303636,0.0002709155,0.00004516196,0.00003122201,7.844765e-7,0.0001085746,0.00000306333,0.00004446254],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5002837,"threshold_uncertainty_score":0.408333,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005121059659616945,"score_gpt":0.1973952871810909,"score_spread":0.192274227521474,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}