{"id":"W2033505236","doi":"10.1039/c3dt50436k","title":"Azide alkyne cycloaddition facilitated by hexanuclear rhenium chalcogenide cluster complexes","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Rhenium; Chemistry; Azide; Cycloaddition; Dimethyl acetylenedicarboxylate; Medicinal chemistry; Pyridine; Ring (chemistry); Iodide; Methyl iodide; Bromide; Cluster (spacecraft); Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00004368539,0.0002445684,0.0002062383,0.00003566932,0.0003800588,0.00007736867,0.0002262983,0.0001849614,0.03587565],"category_scores_gemma":[0.00001159017,0.0002661952,0.0001671959,0.0001836519,0.0001396203,0.0002686003,0.000009131355,0.000345827,0.001612981],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000773885,"about_ca_system_score_gemma":0.0000225168,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003999524,"about_ca_topic_score_gemma":0.00003312793,"domain_scores_codex":[0.998609,0.00001727081,0.0003828532,0.0004231725,0.0001989092,0.0003687609],"domain_scores_gemma":[0.9989954,0.0001293874,0.00008612422,0.0004807371,0.00009048655,0.0002179181],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001325992,0.0002455307,0.00002237114,0.00006940511,0.00006158081,5.383934e-7,0.000192991,0.00009507669,0.9511231,0.00003548238,0.0447761,0.0033646],"study_design_scores_gemma":[0.0005892831,0.0000104803,0.00008809092,0.00002324111,0.00005303886,0.00002321861,0.0004110093,0.001001807,0.6890625,0.0003110048,0.3081068,0.0003195257],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9265735,0.0001321196,0.02204356,0.006200433,0.0001045471,0.000442429,0.004616002,0.0008803693,0.03900709],"genre_scores_gemma":[0.980002,0.00007318798,0.0003240981,0.0002870936,0.00008788577,0.0003367472,0.001761249,0.00004005816,0.01708763],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2633307,"threshold_uncertainty_score":0.999979,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01168151504251921,"score_gpt":0.2271273100929035,"score_spread":0.2154457950503843,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}