{"id":"W2033557715","doi":"10.1002/chin.200609056","title":"Intramolecular Heck‐Type Coupling of Aryl Iodides and Allylic Acetates.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Allylic rearrangement; Aryl; Intramolecular force; Heck reaction; Coupling (piping); Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006024818,0.0007711616,0.0004020139,0.0006292882,0.0005018294,0.0003905609,0.001017241,0.0004169366,0.01533439],"category_scores_gemma":[0.0004637115,0.0004038244,0.0004212003,0.0006908298,0.0004129089,0.0008759687,0.0007446471,0.001250885,0.005414424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005982493,"about_ca_system_score_gemma":0.0008262006,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001021248,"about_ca_topic_score_gemma":0.002797104,"domain_scores_codex":[0.9996262,0.00004583518,0.00001909163,0.00007607996,0.00007941398,0.0001534852],"domain_scores_gemma":[0.9999048,0.00002506725,0.00001460557,0.00001575586,0.0000149666,0.00002470575],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009987695,0.0003859997,0.0005043771,0.002204887,0.0002595489,0.001317525,0.0006886668,0.001688469,0.8718842,0.02011618,0.0218922,0.07805921],"study_design_scores_gemma":[0.0001460314,0.0006651001,0.0008341274,0.00006484115,0.00009308265,0.0007001102,0.00008888329,0.0006808433,0.9459234,0.001145112,0.04960872,0.00004970993],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4606226,0.02492997,0.1107546,0.001824228,0.003505041,0.001033525,0.003051101,0.002782357,0.3914964],"genre_scores_gemma":[0.8532826,0.01771766,0.0175421,0.0003780253,0.0003843704,0.0002324327,0.001620528,0.0001952754,0.108647],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01533439,"threshold_uncertainty_score":0.05129868,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007595338766952018,"score_gpt":0.2299859260345805,"score_spread":0.2223905872676285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}