{"id":"W2033557715","doi":"10.1002/chin.200609056","title":"Intramolecular Heck‐Type Coupling of Aryl Iodides and Allylic Acetates.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Allylic rearrangement; Aryl; Intramolecular force; Heck reaction; Coupling (piping); Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007354265,0.000156162,0.0002061167,0.00003953783,0.00006670648,0.00004953457,0.0001310371,0.000123459,0.0002095393],"category_scores_gemma":[0.0001064722,0.0001635189,0.00006407424,0.0001301739,0.0001993991,0.0001061408,0.0000749535,0.0001573294,0.00001834345],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007310703,"about_ca_system_score_gemma":0.00006538393,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001502318,"about_ca_topic_score_gemma":0.0000111651,"domain_scores_codex":[0.9990989,2.163294e-9,0.0003213855,0.0001851193,0.0001655049,0.0002291138],"domain_scores_gemma":[0.9992983,0.00007547059,0.0001370822,0.0003232234,0.0001028579,0.00006311854],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001775282,0.00003860772,0.001173057,0.0002108882,0.0000309014,0.000005694037,0.00009957737,0.00005296355,0.9950496,0.0001846284,0.0006926506,0.002443691],"study_design_scores_gemma":[0.0003502794,0.000006685493,0.0004728686,0.00005558235,0.00003947663,0.00004262977,0.0001130853,0.0007967125,0.9948418,0.000225409,0.002886616,0.0001689131],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.976739,0.0004682356,0.000001967473,0.00003058405,0.00004405591,0.00004252743,0.00001400091,0.00008297004,0.02257669],"genre_scores_gemma":[0.9973423,0.00004637884,0.00002931703,0.00001439402,0.00008775803,0.000005941077,0.0001309712,0.00002241227,0.002320547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02060331,"threshold_uncertainty_score":0.6668109,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007595338766952018,"score_gpt":0.2299859260345805,"score_spread":0.2223905872676285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}