{"id":"W2033605946","doi":"10.1016/j.tetlet.2014.07.044","title":"Imidazolinium salts derived from amino[2.2]paracyclophane compounds: synthesis and hydrolytic ring-opening","year":2014,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Ring (chemistry); Hydrolysis; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001601334,0.0005081308,0.00061673,0.00005603126,0.0002108463,0.0001445777,0.000572574,0.0002610496,0.001495481],"category_scores_gemma":[0.0002930758,0.0005443707,0.0001450523,0.0001027846,0.0002958647,0.0001873789,0.0002688338,0.000501299,0.0001050255],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00021311,"about_ca_system_score_gemma":0.00002430208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000254025,"about_ca_topic_score_gemma":0.00001146395,"domain_scores_codex":[0.9974753,0.00003385988,0.000576301,0.000867367,0.0003860916,0.0006611173],"domain_scores_gemma":[0.9976025,0.0009502702,0.0002498332,0.0008702765,0.0000223903,0.0003047052],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004890742,0.00004314883,0.004922569,0.0001192222,0.0001209875,0.00002369956,0.0002411334,0.000009233096,0.9907238,0.00001182911,0.0005703779,0.003165055],"study_design_scores_gemma":[0.001138096,0.00001226228,0.003279622,0.0001832867,0.000169153,0.00008934415,0.0001579657,0.0009482556,0.9897355,0.00008175549,0.003495268,0.000709511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.98734,0.00034748,0.0003160238,0.0008958142,0.0002710781,0.00006700795,0.00003144863,0.0003234345,0.01040766],"genre_scores_gemma":[0.9967569,0.00007719376,0.0006455746,0.001350367,0.0008517141,0.00002077227,0.00005583524,0.0001100265,0.0001315911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01027607,"threshold_uncertainty_score":0.9997008,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007374821302289979,"score_gpt":0.205548299959648,"score_spread":0.1981734786573581,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}