{"id":"W2033690048","doi":"10.1021/jp074429p","title":"A Molecule-Based 1:2 Digital Demultiplexer","year":2007,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":97,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Vetenskapsrådet; National Science Foundation","keywords":"Demultiplexer; Porphyrin; Metastability; Molecule; Absorbance; Optoelectronics; Fluorescence; Materials science; Chemistry; Computer science; Photochemistry; Physics; Optics; Multiplexing; Telecommunications","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003876858,0.0001238874,0.0001825565,0.000007609471,0.00006141693,0.00004320756,0.0005094418,0.00004610954,0.0001201679],"category_scores_gemma":[0.0001215103,0.00007560998,0.0001406211,0.00008482338,0.0002302639,0.0001231404,0.00004504429,0.0002504158,0.00003309516],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005723153,"about_ca_system_score_gemma":0.00008943753,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001440198,"about_ca_topic_score_gemma":5.0357e-8,"domain_scores_codex":[0.9990187,0.000009623849,0.0002711727,0.00008905186,0.0003621565,0.0002492946],"domain_scores_gemma":[0.9990788,0.0002302764,0.0002454728,0.0002092167,0.00009039376,0.0001459143],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001813469,0.0001310185,0.00003136837,0.00002211174,0.000006105023,0.00002183392,0.0001106177,0.00007200852,0.999048,0.000004039141,0.0002558539,0.0001157195],"study_design_scores_gemma":[0.0004068311,0.00003012073,0.00007226381,0.000038133,0.0000225584,0.00006879183,0.00009758052,0.0003307365,0.9984903,0.0001942456,0.0001526562,0.00009579147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956486,0.00003322728,0.001458523,0.0001006706,0.00002918527,0.00003300891,0.000008818593,0.00001446588,0.002673553],"genre_scores_gemma":[0.9991508,6.00909e-7,0.0001020922,0.00006951432,0.0005604296,4.960194e-7,0.000001416363,0.00001053252,0.0001041216],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003502249,"threshold_uncertainty_score":0.3083285,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008043235106730277,"score_gpt":0.2398968272934009,"score_spread":0.2318535921866707,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}