{"id":"W2033987496","doi":"10.1007/s11244-010-9542-4","title":"SiliaCat ® TEMPO: An Effective and Recyclable Oxidizing Catalyst","year":2010,"lang":"en","type":"article","venue":"Topics in Catalysis","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"SiliCycle (Canada)","funders":"","keywords":"Oxidizing agent; Reusability; Catalysis; Homogeneous; Chemistry; Selectivity; Radical; Alcohol oxidation; Organic chemistry; Combinatorial chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002630772,0.0004194469,0.0002454729,0.0003804387,0.0001249416,0.0003450574,0.0005843574,0.0003650096,0.001920316],"category_scores_gemma":[0.0001885744,0.0001468847,0.00023861,0.0002253588,0.0001761175,0.0005805148,0.0003565623,0.0005556928,0.0008625819],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001732925,"about_ca_system_score_gemma":0.0002077745,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002515451,"about_ca_topic_score_gemma":0.0002945828,"domain_scores_codex":[0.9998715,0.00001522337,0.00001049772,0.00002882036,0.00004358734,0.00003032073],"domain_scores_gemma":[0.9999493,0.000006601798,0.00001640096,0.000006124549,0.000008620088,0.00001288741],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002701902,0.00007340906,0.0001364621,0.0002453479,0.00002340993,0.0001547626,0.00003893813,0.0002210026,0.9744619,0.001244326,0.0006526569,0.02247768],"study_design_scores_gemma":[0.00003762677,0.000499329,0.0003501464,0.000006511434,0.0000586407,0.0003021043,0.0000119467,0.0009653126,0.9882507,0.0001408554,0.009366826,0.00001010413],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9179252,0.009861366,0.05141566,0.0005469851,0.0004910958,0.0001181682,0.0003733293,0.001195534,0.01807269],"genre_scores_gemma":[0.9731823,0.003402569,0.008258943,0.00009706942,0.0001267933,0.00003065468,0.0003455283,0.00008343093,0.01447282],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001920316,"threshold_uncertainty_score":0.006424069,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007802927791733153,"score_gpt":0.2576530753516064,"score_spread":0.2498501475598733,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}