{"id":"W2034048520","doi":"10.1021/jo501835u","title":"Iridium-Catalyzed Annulative Coupling of 2-Arylbenzoyl Chlorides with Alkynes: Selective Formation of Phenanthrene Derivatives","year":2014,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; Ministry of Education, Culture, Sports, Science and Technology; Ryerson University","keywords":"Chemistry; Phenanthrene; Iridium; Catalysis; Coupling (piping); Phenanthrenes; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000864614,0.0002062543,0.0004696925,0.00004535006,0.00008838339,0.00001141953,0.0003580838,0.00009839143,0.0006380357],"category_scores_gemma":[0.0009567,0.0001406181,0.0001063619,0.0004054286,0.0002611795,0.0002681248,0.00006555248,0.0002794471,9.675945e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001344684,"about_ca_system_score_gemma":0.000238052,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009157225,"about_ca_topic_score_gemma":0.000002762397,"domain_scores_codex":[0.9983454,0.00001828382,0.0008261912,0.0001266825,0.0005185078,0.0001649126],"domain_scores_gemma":[0.9959314,0.000756012,0.001894622,0.0003249071,0.001022257,0.00007082859],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005627081,0.00007670055,0.0008374003,0.0003628769,0.0002001939,5.649823e-7,0.002507375,0.001598576,0.9936509,0.00001331705,0.00004071227,0.0001487251],"study_design_scores_gemma":[0.001226982,0.00004694987,0.0003930786,0.0003355453,0.0002652812,0.0001678695,0.003760351,0.001304882,0.9920416,0.000280978,0.0000297672,0.0001467031],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9397938,0.0002267556,0.05916819,0.00008326156,0.00003929602,0.00004901299,0.0000191471,0.00001431291,0.0006062762],"genre_scores_gemma":[0.9985734,0.00007386225,0.0009812701,0.000008770244,0.0002180447,0.000001225393,0.00002745379,0.00003144823,0.00008456386],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05877962,"threshold_uncertainty_score":0.6986043,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01298240961364363,"score_gpt":0.2477503221728197,"score_spread":0.234767912559176,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}