{"id":"W2034102012","doi":"10.1021/jo701289d","title":"Carbon-Centered Strong Bases in Phosphonium Ionic Liquids","year":2008,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":101,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; Simon Fraser University","funders":"","keywords":"Phosphonium; Chemistry; Ionic liquid; Reagent; Inorganic chemistry; Reactivity (psychology); Electrochemistry; Decomposition; Organic chemistry; Catalysis; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001733409,0.0004464903,0.0002048471,0.0002354308,0.000186173,0.0004737624,0.0004565633,0.0004305716,0.002046793],"category_scores_gemma":[0.0001972572,0.0003125658,0.0002126559,0.00017923,0.000264385,0.0006584072,0.0006131276,0.0008316985,0.001424863],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004378494,"about_ca_system_score_gemma":0.0002227625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003049524,"about_ca_topic_score_gemma":0.0005231762,"domain_scores_codex":[0.9998502,0.00001738919,0.00001347002,0.00002969145,0.00005826203,0.00003098856],"domain_scores_gemma":[0.9999175,0.00001853012,0.00002331288,0.000009349423,0.00001554923,0.00001577144],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007277061,0.00004510732,0.0001189633,0.0002872638,0.000009746437,0.0001809888,0.00005950363,0.001192911,0.9730582,0.01075425,0.0006661177,0.01355421],"study_design_scores_gemma":[0.00001298227,0.0001201912,0.0001057716,0.00001906775,0.000006718607,0.00008934647,0.000009318723,0.001294984,0.9859262,0.0005318588,0.01187566,0.000007894258],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.873642,0.01238461,0.0510826,0.0007002598,0.0004854709,0.0001949675,0.0006804938,0.001465044,0.0593646],"genre_scores_gemma":[0.9581051,0.0050928,0.02269831,0.0002458856,0.00008986728,0.0001387943,0.0003850554,0.0001792798,0.01306494],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002046793,"threshold_uncertainty_score":0.006847203,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0141504234764472,"score_gpt":0.2188069244479097,"score_spread":0.2046565009714625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}