{"id":"W2034154334","doi":"10.1039/b910887d","title":"Effect of steric bulk on the absolute reactivity of allene oxides","year":2009,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Allene; Chemistry; Reactivity (psychology); Steric effects; Photochemistry; Alkyl; Derivative (finance); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000326911,0.0003560772,0.0001710568,0.0001437244,0.0001659093,0.0002562155,0.0002035141,0.0002300259,0.001492009],"category_scores_gemma":[0.0005134625,0.0001839492,0.0001474815,0.00009333941,0.0002854273,0.0003069139,0.0001665244,0.0003509361,0.0002488351],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000209002,"about_ca_system_score_gemma":0.0001816632,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006762114,"about_ca_topic_score_gemma":0.001397853,"domain_scores_codex":[0.9998118,0.00003871483,0.00001310792,0.00003636575,0.00004685576,0.00005320838],"domain_scores_gemma":[0.9994961,0.0002336469,0.0001163658,0.00003347707,0.00008315877,0.00003716881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000185663,0.000009104029,0.0003265355,0.00005017412,0.00001044486,0.00008161542,0.00003950976,0.0002712426,0.9978517,0.0001283674,0.00002993937,0.001015662],"study_design_scores_gemma":[0.000007074161,0.0002185371,0.0008765027,0.000004175208,0.00001113822,0.00006955543,0.00002008183,0.00037233,0.9980417,0.00002478909,0.0003491787,0.00000487534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974807,0.0003416819,0.0004477531,0.0000321383,0.000006843893,0.000005722127,0.00007031678,0.00001619613,0.001598651],"genre_scores_gemma":[0.9986823,0.0002917835,0.0003278715,0.00001983042,0.000004578707,0.00000491591,0.0001088241,0.0000104456,0.0005495807],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001492009,"threshold_uncertainty_score":0.004991293,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003906722000012216,"score_gpt":0.226502184511548,"score_spread":0.2225954625115358,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}