{"id":"W2034363894","doi":"10.1021/ic001163r","title":"Synthesis of 14-oxa-1,4,8,11-tetraazabicyclo[9.5.3]nonadecane (L1) and a Spectroscopic and Structural Study of [Ni(L1)(ClO<sub>4</sub>)](ClO<sub>4</sub>) and of the Macrobicyclic Precursor Diamide Complex, [Ni(HL2)](ClO<sub>4</sub>); Chloride Substitution Kinetics of the Corresponding [Ni(III)(L1)]<sup>3+</sup> Species","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria; University of British Columbia; Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Crystal structure; Stereochemistry; X-ray crystallography; Crystallography; Diffraction","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000605973,0.0002089339,0.0002124319,0.0001304362,0.0001924305,0.0001717008,0.000238701,0.0001626865,0.002763118],"category_scores_gemma":[0.0001297162,0.0001316628,0.00007774519,0.0002344025,0.0001113731,0.0001801408,0.0001650395,0.0002838652,0.0009692767],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00041389,"about_ca_system_score_gemma":0.0006695655,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001043201,"about_ca_topic_score_gemma":0.003748934,"domain_scores_codex":[0.9999485,0.000004935205,0.000004295131,0.00001622184,0.00001385018,0.00001218862],"domain_scores_gemma":[0.9999278,0.000006428484,0.00001975165,0.000007443196,0.00001728965,0.00002126909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001619002,0.00003044883,0.0001692217,0.0001416711,0.000006309051,0.00008068641,0.0000540348,0.0007179523,0.990481,0.0006566622,0.000130307,0.007369977],"study_design_scores_gemma":[0.00002033868,0.0003031757,0.0007735677,0.000006828488,0.00001012019,0.0001944681,0.00003237956,0.0007075508,0.9816577,0.0001076291,0.01617482,0.00001136103],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9707085,0.002869462,0.01218224,0.0001326168,0.00007001518,0.0001972581,0.001459222,0.0002570903,0.01212344],"genre_scores_gemma":[0.9689613,0.001359052,0.01745304,0.0000767092,0.000009510424,0.0001725536,0.00167819,0.00007867582,0.01021102],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002763118,"threshold_uncertainty_score":0.009243548,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008802975175377217,"score_gpt":0.2149262740181511,"score_spread":0.2061232988427739,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}