{"id":"W2034423242","doi":"10.1021/ol060399h","title":"A Concise, Enantioselective Approach to (−)-Quinic Acid","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Quinic acid; Enantioselective synthesis; Chemistry; Morpholine; Metathesis; Stereochemistry; Ephedrine; Alkylation; Ring-closing metathesis; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002597051,0.0003490281,0.0003638895,0.00005758891,0.0001147753,0.00006775111,0.0005412067,0.0001779651,0.002791637],"category_scores_gemma":[0.0002841631,0.000352995,0.0001334572,0.0004889045,0.00009447956,0.00007477967,0.0001446325,0.0003280414,0.0003868858],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004033574,"about_ca_system_score_gemma":0.00009673303,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004476259,"about_ca_topic_score_gemma":0.000003010647,"domain_scores_codex":[0.997812,0.00004384902,0.0003901223,0.0007424185,0.000381815,0.0006297786],"domain_scores_gemma":[0.9987349,0.0001437802,0.0001240294,0.0007724033,0.00005287445,0.0001720132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001777773,0.0001151247,0.0002826367,0.00004887329,0.00004185853,0.00001147456,0.0001998196,0.000002839913,0.9833782,0.00007730912,0.01529611,0.000527919],"study_design_scores_gemma":[0.0006060257,0.000007839565,0.0001953371,0.00002304814,0.00005155497,0.0001201461,0.000132861,0.00002414886,0.9923058,0.00008035464,0.006014483,0.0004384137],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9129206,0.00009195739,0.01789057,0.002631447,0.0001750394,0.0001599375,0.00002214188,0.0004525847,0.06565571],"genre_scores_gemma":[0.9824042,0.000001629048,0.01344853,0.001784894,0.0007265424,0.00004005438,0.00003018199,0.0001147874,0.001449178],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06948359,"threshold_uncertainty_score":0.9998922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009840019270179695,"score_gpt":0.2302639673028312,"score_spread":0.2204239480326516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}