{"id":"W2034470219","doi":"10.1021/jp0031911","title":"Kinetic Study of the Mechanism of the Low-Temperature Pyrolysis of Vinyl Bromide","year":2001,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Combustion Engine Technologies","field":"Chemical Engineering","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Vinyl bromide; Activation energy; Chemistry; Arrhenius equation; Atmospheric temperature range; Disproportionation; Bromide; Thermal decomposition; Extrapolation; Pyrolysis; Kinetic energy; Allyl bromide; Reaction rate constant; Decomposition; Thermodynamics; Physical chemistry; Bond cleavage; Kinetics; Polymer chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004530387,0.000504931,0.0007049136,0.0002725238,0.0003024629,0.0004325752,0.0006552465,0.000387773,0.001492675],"category_scores_gemma":[0.0006679991,0.0002675764,0.0005843802,0.0002258645,0.0003857849,0.0006217166,0.0001996859,0.0007265273,0.0006608517],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005701728,"about_ca_system_score_gemma":0.0003185773,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001680786,"about_ca_topic_score_gemma":0.001022541,"domain_scores_codex":[0.9997522,0.00003234466,0.0000112523,0.00004256818,0.0001079401,0.00005372631],"domain_scores_gemma":[0.9996495,0.0001605732,0.00006737171,0.00002260254,0.00007396337,0.00002598808],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001990684,0.00006578519,0.00216613,0.0002955502,0.00003326104,0.0001713377,0.00007502393,0.0046392,0.9882405,0.0005320188,0.00006987579,0.003512289],"study_design_scores_gemma":[0.00002412663,0.0002152463,0.008199346,0.0000186661,0.00002555079,0.0002316544,0.00005646283,0.03360834,0.9565502,0.0002979822,0.0007369014,0.00003545721],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851195,0.001710792,0.01084099,0.00009454918,0.00001992203,0.00004741833,0.0003173702,0.000108508,0.001740868],"genre_scores_gemma":[0.9956484,0.0009422743,0.002135713,0.00001211603,0.000005557311,0.00002571837,0.0002184157,0.0000215338,0.0009902449],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001680786,"threshold_uncertainty_score":0.004993498,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005531701911349633,"score_gpt":0.2155702055128362,"score_spread":0.2100385036014866,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}