{"id":"W2034748698","doi":"10.1021/om060742m","title":"Catalytic Alkene Hydroboration Mediated by Cationic and Formally Zwitterionic Rhodium(I) and Iridium(I) Derivatives of a P,N-Substituted Indene","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Mount Allison University; University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Hydroboration; Indene; Iridium; Cationic polymerization; Rhodium; Alkene; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001904678,0.0003905623,0.0002393338,0.000100097,0.0001180075,0.0002338732,0.0003755177,0.0002379073,0.001170829],"category_scores_gemma":[0.000175221,0.0002166709,0.000149814,0.0000866904,0.000291269,0.0002494874,0.0002883432,0.0002873994,0.0003550028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000229637,"about_ca_system_score_gemma":0.0001674703,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005114109,"about_ca_topic_score_gemma":0.001377093,"domain_scores_codex":[0.9998857,0.00001682598,0.000006852626,0.00002544055,0.00002374461,0.00004156318],"domain_scores_gemma":[0.9999326,0.00001119019,0.00002017188,0.00001128081,0.000007401667,0.00001733805],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001361339,0.00001218552,0.00006157099,0.00005862932,0.000007108807,0.00003614029,0.00003717924,0.0000595798,0.9979664,0.0002220954,0.00003969094,0.001363304],"study_design_scores_gemma":[0.00001273861,0.00007601334,0.0002466671,0.000001825698,0.000005623566,0.000066362,0.00001183145,0.000129107,0.998727,0.00001823412,0.0007009826,0.000003568704],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920018,0.0009358897,0.003197393,0.00005162678,0.00002141589,0.00004827138,0.00009643653,0.00011333,0.003533903],"genre_scores_gemma":[0.9965773,0.0003915411,0.001150571,0.00001795779,0.000003324345,0.00001276265,0.00007449567,0.00001974199,0.001752182],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001170829,"threshold_uncertainty_score":0.00391686,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005153982394126013,"score_gpt":0.1952352963672659,"score_spread":0.1900813139731399,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}