{"id":"W2034748698","doi":"10.1021/om060742m","title":"Catalytic Alkene Hydroboration Mediated by Cationic and Formally Zwitterionic Rhodium(I) and Iridium(I) Derivatives of a P,N-Substituted Indene","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Mount Allison University; University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Hydroboration; Indene; Iridium; Cationic polymerization; Rhodium; Alkene; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001162311,0.0003142598,0.0003875619,0.00008441103,0.0001370955,0.00007706486,0.0002506217,0.000253158,0.0003855759],"category_scores_gemma":[0.0001499764,0.0003252331,0.00004315543,0.0003886965,0.0003199247,0.0003349046,0.0001637979,0.000191967,0.00001210284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009374979,"about_ca_system_score_gemma":0.0001506161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001030861,"about_ca_topic_score_gemma":0.0000834081,"domain_scores_codex":[0.9984246,0.00001733053,0.0005545317,0.0004330373,0.000257899,0.000312561],"domain_scores_gemma":[0.9988773,0.00009339274,0.0003130067,0.0004577071,0.0001222999,0.0001362829],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001755612,0.0001225126,0.009270575,0.000260681,0.00005571111,0.000002522861,0.0001777081,0.000003299273,0.9892766,0.0001740868,0.0002590249,0.0003796613],"study_design_scores_gemma":[0.001084461,0.00002023653,0.007926323,0.00003518258,0.0000795775,0.00003219598,0.0001041052,0.0002018813,0.9889186,0.0001740205,0.001081537,0.0003418692],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958739,0.001642971,0.00014272,0.0005047275,0.0000320607,0.0001078205,0.0001159184,0.0001002896,0.001479594],"genre_scores_gemma":[0.9976476,0.0004349932,0.0003185908,0.00006098061,0.00007194006,0.00001519713,0.0009664045,0.00005209415,0.0004321989],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001773703,"threshold_uncertainty_score":0.99992,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005153982394126013,"score_gpt":0.1952352963672659,"score_spread":0.1900813139731399,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}