{"id":"W2034876407","doi":"10.1139/v05-241","title":"The synthesis and characterization of the pendant-armed ligand <i>N</i>,<i>N′</i>-bis(2′-pyridylmethyl)-1,7-dithia-4,11-diazacyclotetradecane (L<sub>4</sub>) and crystal structures of L<sub>4</sub> and the copper(II) complex [Cu(L<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub> Crystal structure of the nickel(II) complex of <i>N</i>-(2′-pyridylmethyl)-1,4,7-trithia-11-azacyclotetradecane (L<sub>2</sub>), [Ni(L<sub>2</sub>)(CH<sub>3</sub>CN)](ClO<sub>4</sub>)<sub>2</sub>·CH<sub>3</sub>CN","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Thioether; Ligand (biochemistry); Pyridine; Acetonitrile; Crystal structure; Nickel; Amine gas treating; Crystallography; Octahedron; Copper; Electrochemistry; Molecule; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008148894,0.0001776806,0.0001571949,0.0001085324,0.0001703444,0.0002006203,0.0003029619,0.0002037426,0.001223033],"category_scores_gemma":[0.000175999,0.0001009728,0.00008613895,0.000161132,0.0001663556,0.0001376906,0.0001460168,0.0002309689,0.0004277464],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005740246,"about_ca_system_score_gemma":0.0005028188,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002440673,"about_ca_topic_score_gemma":0.005110506,"domain_scores_codex":[0.9999357,0.000006472859,0.000003666095,0.00001895912,0.00002330228,0.00001187824],"domain_scores_gemma":[0.9999208,0.0000117874,0.00002055267,0.00001222161,0.00001658545,0.00001808437],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001971998,0.000008189243,0.0001125165,0.00003864281,0.000001508114,0.00003236913,0.00001762103,0.0001969847,0.9975895,0.0001190193,0.0000542843,0.001809643],"study_design_scores_gemma":[0.000003344794,0.00005751802,0.0006136502,0.000001607944,0.000002539039,0.00007533841,0.00001415224,0.0003343539,0.995138,0.00002100262,0.003735394,0.000003179503],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792685,0.0009082163,0.01363856,0.000115309,0.00001451723,0.00009276479,0.0009305165,0.0001910462,0.004840493],"genre_scores_gemma":[0.9729816,0.0008127149,0.01658792,0.00005928631,0.000006598044,0.0001122202,0.001463458,0.00004766325,0.007928493],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002440673,"threshold_uncertainty_score":0.004852951,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008485086675085766,"score_gpt":0.1937234161403746,"score_spread":0.1852383294652889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}