{"id":"W2035108179","doi":"10.1016/j.jasms.2004.11.012","title":"Investigation of electrospray ionization and electrostatic focusing devices using a three-dimensional electrospray current density profiler","year":2005,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"McMaster University","keywords":"Chemistry; Quadrupole mass analyzer; Mass spectrometry; Analytical Chemistry (journal); Electrospray; Quadrupole; Electrospray ionization; Ionization; Ion current; Ion; Spectrometer; Triple quadrupole mass spectrometer; Atomic physics; Chromatography; Optics; Tandem mass spectrometry; Selected reaction monitoring","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001380146,0.000516556,0.0003974595,0.0004567389,0.0004143592,0.0008963153,0.001008065,0.000896786,0.0008994906],"category_scores_gemma":[0.00248128,0.0002929329,0.0003183475,0.0003679114,0.0005848352,0.001430311,0.0003387667,0.0004179069,0.0004046274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006494694,"about_ca_system_score_gemma":0.0004932478,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004701546,"about_ca_topic_score_gemma":0.0004134635,"domain_scores_codex":[0.9989405,0.00007811352,0.00005662792,0.0001398246,0.0006942446,0.00009064723],"domain_scores_gemma":[0.9983085,0.0007861617,0.0002022482,0.0001252801,0.0004903268,0.00008756072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002321826,0.00009271776,0.001326558,0.0001740217,0.00002135714,0.0002337375,0.0001879098,0.0005308345,0.9802312,0.001743327,0.0003867483,0.01483942],"study_design_scores_gemma":[0.00004254252,0.0007579599,0.00611979,0.00002965689,0.00002890058,0.0008473045,0.00008591932,0.00830621,0.9767677,0.0003959058,0.006583609,0.00003462791],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9294022,0.00495092,0.06052521,0.0005307287,0.0001224924,0.000302265,0.0004055632,0.0005036519,0.003256872],"genre_scores_gemma":[0.9486564,0.002670143,0.04395358,0.0003211078,0.00005962764,0.0002757869,0.0006150967,0.00009840146,0.003349909],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001380146,"threshold_uncertainty_score":0.007299006,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01801293407146276,"score_gpt":0.2777773584716875,"score_spread":0.2597644244002247,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}