{"id":"W2035153957","doi":"10.1039/c3cc47856d","title":"Enhanced stereoselectivity in a di-Ru(<scp>ii</scp>) complex of an achiral bis-bidentate ligand","year":2013,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Denticity; Ligand (biochemistry); Chemistry; Stereoselectivity; Stereochemistry; Electrochemistry; Crystallography; Receptor; Crystal structure; Catalysis; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001915738,0.0001487512,0.0004216872,0.00009319565,0.0001091296,0.00002544363,0.0005849291,0.00008083545,0.00002883546],"category_scores_gemma":[0.0004069858,0.0001248051,0.00009366922,0.000275511,0.0002952085,0.000183599,0.0004103543,0.0003275464,0.00003001946],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004339504,"about_ca_system_score_gemma":0.00004992233,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004096064,"about_ca_topic_score_gemma":0.0001062929,"domain_scores_codex":[0.9988195,0.0001552744,0.000427764,0.0001997233,0.0001690232,0.000228771],"domain_scores_gemma":[0.997866,0.000379747,0.0001228651,0.001355846,0.0001439708,0.0001315762],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001568538,0.0005452567,0.001270719,0.00004299739,0.00002730238,2.40162e-7,0.0007556456,5.347524e-7,0.9946858,0.0001966533,0.0001573321,0.00230189],"study_design_scores_gemma":[0.0005702376,0.0001552809,0.04290149,0.00008740007,0.00003520045,0.000009480968,0.0003067887,0.001442637,0.9527124,0.000737121,0.0009712421,0.00007071683],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883701,0.0004629247,0.00006302052,0.0005792132,0.00001353497,0.0004170632,0.000009623265,0.00004554759,0.01003896],"genre_scores_gemma":[0.9959116,0.0000991678,0.003124185,0.0001803685,0.00002242481,0.0001159946,0.00008594196,0.00002033718,0.0004399626],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04197334,"threshold_uncertainty_score":0.5089403,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08827510205238566,"score_gpt":0.3218866500663649,"score_spread":0.2336115480139793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}